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Characterization of Simulated Postconsumer Recycled Poly (Lactic Acid) (PLA): Evaluation of Reprocessing Cycles on Its Physicochemical Properties
Indexado
WoS WOS:001449615500001
Scopus SCOPUS_ID:105003926241
DOI 10.1002/POL.20241028
Año 2025
Tipo artículo de investigación

Citas Totales

Autores Afiliación Chile

Instituciones Chile

% Participación
Internacional

Autores
Afiliación Extranjera

Instituciones
Extranjeras


Abstract



This study aims to investigate the behavior of poly (lactic acid) (PLA) by simulating its post-consumption use and mechanical recycling through multiple extrusion processes. Due to PLA being used in the production of packaging materials for beverages such as water and juice, the plastic was exposed to food simulants A and B according to international regulatory standards, and these materials were then subjected to repeated extrusion cycles, with a maximum of five cycles. After each cycle, the material's properties were evaluated through physicochemical characterization, including determination of the mean molecular weight by viscosity (Mv), melt flow index (MFI), structural analysis via infrared spectroscopy (FTIR), IZOD impact strength, thermal behavior using differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA), and color evaluation using the CIELAB scale. Although a change in the molecular weight of the PLA samples was observed after different initial treatments and reprocessing, these did not significantly affect the thermal and mechanical properties of the materials. However, a noticeable color change occurred after the reprocessing cycles. This would indicate polyester degradation through various mechanisms and the generation of chromophore species.

Revista



Revista ISSN
2642-4150

Métricas Externas



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Disciplinas de Investigación



WOS
Polymer Science
Scopus
Sin Disciplinas
SciELO
Sin Disciplinas

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Publicaciones WoS (Ediciones: ISSHP, ISTP, AHCI, SSCI, SCI), Scopus, SciELO Chile.

Colaboración Institucional



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Autores - Afiliación



Ord. Autor Género Institución - País
1 Silva, Tannia - Universidad de Santiago de Chile - Chile
Centro para el Desarrollo de la Nanociencia y la Nanotecnologia - Chile
2 Rodriguez-Mercado, Francisco - Universidad de Santiago de Chile - Chile
Centro para el Desarrollo de la Nanociencia y la Nanotecnologia - Chile
3 BRUNA-BUGUENO, JULIO ELIAS Hombre Universidad de Santiago de Chile - Chile
Centro para el Desarrollo de la Nanociencia y la Nanotecnologia - Chile
4 Torres, Alejandra - Universidad de Santiago de Chile - Chile
Centro para el Desarrollo de la Nanociencia y la Nanotecnologia - Chile
5 Arrieta, M. P. Mujer Univ Politecn Madrid - España
Grp Invest Polimeros Caracterizac & Aplicac POLCA - España
Escuela Tecnica Superior de Ingenieros Industriales - España
Grupo de Investigación: Polímeros - España
6 Faba, S. Hombre Univ Politecn Madrid - España
Grp Invest Polimeros Caracterizac & Aplicac POLCA - España
Escuela Tecnica Superior de Ingenieros Industriales - España
Grupo de Investigación: Polímeros - España
7 GALOTTO-LOPEZ, MARIA JOSE Mujer Universidad de Santiago de Chile - Chile
Centro para el Desarrollo de la Nanociencia y la Nanotecnologia - Chile
8 GUARDA-MORAGA, ABEL Hombre Universidad de Santiago de Chile - Chile
Centro para el Desarrollo de la Nanociencia y la Nanotecnologia - Chile
9 ROMERO-REYES, JOSE MARIO LUIS Hombre Universidad de Santiago de Chile - Chile

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Financiamiento



Fuente
FONDEQUIP
Fondo Nacional de Desarrollo Científico y Tecnológico
Comisión Nacional de Investigación Científica y Tecnológica
European Commission
European Union
European Regional Development Fund
Ministerio de Ciencia e Innovación
Spanish Ministry of Science and Innovation (MICINN)
Agencia Estatal de Investigación
Center for the Development of Nanoscience and Nanotechnology (CEDENNA)
Centro para el Desarrollo de la Nanociencia y la Nanotecnologia
National Agency for Research and Development (ANID)
Agencia Nacional de Investigación y Desarrollo
ANID-Chile
Agenția Națională pentru Cercetare și Dezvoltare
PRTR
European Union Next Generation EU
TED-AEI
TED‐AEI

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Agradecimientos



Agradecimiento
This work was supported by the National Agency for Research and Development (ANID) (grant number 21212139) under project FOVI220086, FONDECYT 1211391, FONDEQUIP EQM190104, the Center for the Development of Nanoscience and Nanotechnology (CEDENNA) (AFB220001), the Spanish Ministry of Science and Innovation (MICINN) (grant PID2021-123753NA-C32), European Union, TED-AEI (grant TED-129920A-C43), Research consolidation (grant CNS2022- 136064), and Postdoctoral Scholarship abroad (grant number 74230053).
Funding: This work was supported by the National Agency for Research and Development (ANID) (grant number 21212139) under project FOVI220086, FONDECYT 1211391, FONDEQUIP EQM190104, the Center for the Development of Nanoscience and Nanotechnology (CEDENNA) (AFB220001), the Spanish Ministry of Science and Innovation (MICINN) (grant PID2021-123753NA-C32), European Union, TED-AEI (grant TED-129920A-C43), Research consolidation (grant CNS2022-136064), and Postdoctoral Scholarship abroad (grant number 74230053). The authors thanks to the Agencia Nacional de Investigaci\u00F3n y Desarrollo (ANID-Chile) for funding through the doctoral fellowship ANID-PFCHA/Doctorado Nacional 2021 [grant number 21212139], the project FOVI220086, FONDECYT 1211391, FONDEQUIP EQM190104 and the Center for the Development of Nanoscience and Nanotechnology (CEDENNA) [AFB220001]. The Spanish Ministry of Science and Innovation (MICINN) through the PID-AEI project [grant PID2021-123753NA-C32] funded by MCIN/AEI/10.13039/501100011033 and by ERDF \u201CA way of making Europe\u201D by the European Union as well as the TED-AEI project [grant TED-129920A-C43] and Research consolidation project [grant CNS2022-136064] funded by MCIN/AEI/10.13039/501100011033 and by the \u201CEuropean Union Next Generation EU/PRTR\u201D. Sim\u00F3n Faba gratefully acknowledges the National Commission for Scientific and Technological Research, ANID, for its financial support from the Postdoctoral Scholarship abroad [grant number 74230053].
The authors thanks to the Agencia Nacional de Investigaci\u00F3n y Desarrollo (ANID\u2010Chile) for funding through the doctoral fellowship ANID\u2010PFCHA/Doctorado Nacional 2021 [grant number 21212139], the project FOVI220086, FONDECYT 1211391, FONDEQUIP EQM190104 and the Center for the Development of Nanoscience and Nanotechnology (CEDENNA) [AFB220001]. The Spanish Ministry of Science and Innovation (MICINN) through the PID\u2010AEI project [grant PID2021\u2010123753NA\u2010C32] funded by MCIN/AEI/ 10.13039/501100011033 and by ERDF \u201CA way of making Europe\u201D by the European Union as well as the TED\u2010AEI project [grant TED\u2010129920A\u2010C43] and Research consolidation project [grant CNS2022\u2010136064] funded by MCIN/AEI/ 10.13039/501100011033 and by the \u201CEuropean Union Next Generation EU/PRTR\u201D. Sim\u00F3n Faba gratefully acknowledges the National Commission for Scientific and Technological Research, ANID, for its financial support from the Postdoctoral Scholarship abroad [grant number 74230053].
This work was supported by the National Agency for Research and Development (ANID) (grant number 21212139) under project FOVI220086, FONDECYT 1211391, FONDEQUIP EQM190104, the Center for the Development of Nanoscience and Nanotechnology (CEDENNA) (AFB220001), the Spanish Ministry of Science and Innovation (MICINN) (grant PID2021\u2010123753NA\u2010C32), European Union, TED\u2010AEI (grant TED\u2010129920A\u2010C43), Research consolidation (grant CNS2022\u2010136064), and Postdoctoral Scholarship abroad (grant number 74230053). Funding:

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