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Origin of fumarolic fluids from Tupungatito Volcano (Central Chile): interplay between magmatic, hydrothermal, and shallow meteoric sources
Indexado
WoS WOS:000323104100001
Scopus SCOPUS_ID:84880335583
DOI 10.1007/S00445-013-0746-X
Año 2013
Tipo artículo de investigación

Citas Totales

Autores Afiliación Chile

Instituciones Chile

% Participación
Internacional

Autores
Afiliación Extranjera

Instituciones
Extranjeras


Abstract



Tupungatito is a poorly known volcano located about 100 km eastward of Santiago (Chile) in the northernmost sector of the South Volcanic Zone. This 5,682 m high volcano shows intense fumarolic activity. It hosts three crater lakes within the northwestern portion of the summit area. Chemical compositions of fumarolic gases and isotopic signatures of noble gases (He-3/He-4 and Ar-40/Ar-36 are up to 6.09 Ra and 461, respectively), and steam (delta O-18 and delta D) suggest that they are produced by mixing of fluids from a magmatic source rich in acidic gas compounds (SO2, HCl, and HF), and meteoric water. The magmatic-hydrothermal fluids are affected by steam condensation that controls the outlet fumarolic temperatures (<83.6 degrees C), the gas chemical composition, and the steam isotopic values. The delta C-13-CO2 values (ranging from 0.30 and -8.16% vs. V-PDB) suggest that CO2 mainly derives from (1) a mantle source likely affected by significant contamination from the subducting slab, (2) the sedimentary basement, and (3) limited contribution from crustal sediments. Gas geothermometry based on the kinetically rapid H-2-CO equilibria indicates equilibrium temperatures <200 degrees C attained in a single vapor phase at redox conditions slightly more oxidizing than those commonly characterizing hydrothermal reservoirs. Reactions in the H2O-CO2-H-2-CO-CH4 system and C-2-C-3 alkenes/alkanes pairs, which have relatively slow kinetics, seem to equilibrate at greater depth, where temperatures are > 200 degrees C and redox conditions are consistent with those inferred by the presence of the SO2-H2S redox pair, typical of fluids that have attained equilibrium in magmatic environment. A comprehensive conceptual geochemical model describing the circulation pattern of the Tupungatito hydrothermal-magmatic fluids is proposed. It includes fluid source regions and re-equilibration processes affecting the different gas species due to changing chemical-physical conditions as the magmatic-hydrothermal fluids rise up toward the surface.

Revista



Revista ISSN
Bulletin Of Volcanology 0258-8900

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Disciplinas de Investigación



WOS
Geosciences, Multidisciplinary
Scopus
Sin Disciplinas
SciELO
Sin Disciplinas

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Publicaciones WoS (Ediciones: ISSHP, ISTP, AHCI, SSCI, SCI), Scopus, SciELO Chile.

Colaboración Institucional



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Autores - Afiliación



Ord. Autor Género Institución - País
1 BENAVENTE-ZOLEZZI, OSCAR MATIAS Hombre Universidad de Chile - Chile
Centro de Excelencia en Geotermia de Los Andes - Chile
2 Tassi, Franco Hombre UNIV FLORENCE - Italia
Università degli Studi di Firenze - Italia
3 GUTIERREZ-FERRER, FRANCISCO JAVIER Hombre Universidad de Chile - Chile
Centro de Excelencia en Geotermia de Los Andes - Chile
4 Vaselli, O. Hombre UNIV FLORENCE - Italia
Università degli Studi di Firenze - Italia
5 AGUILERA-VALENZUELA, FELIPE IGNACIO Hombre Universidad de Chile - Chile
Universidad de Atacama - Chile
Centro de Excelencia en Geotermia de Los Andes - Chile
6 REICH-MORALES, MARTIN HERBERT Hombre Universidad de Chile - Chile
Centro de Excelencia en Geotermia de Los Andes - Chile

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Origen de Citas Identificadas



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Citas identificadas: Las citas provienen de documentos incluidos en la base de datos de DATACIENCIA

Citas Identificadas: 17.24 %
Citas No-identificadas: 82.76 %

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Citas identificadas: Las citas provienen de documentos incluidos en la base de datos de DATACIENCIA

Citas Identificadas: 17.24 %
Citas No-identificadas: 82.76 %

Financiamiento



Fuente
FONDAP
MECESUP
Comisión Nacional de Investigación Científica y Tecnológica
Comisión Nacional de Investigación Científica y Tecnológica
Fondo de Financiamiento de Centros de Investigación en Áreas Prioritarias
MECESUP Doctoral Fellowship
Chilean National Commission for Science and Technology
CONICYT (Chilean National Commission for Science and Technology)
University of Florence
FONDAP Proyect
PBCT-PDA07 project

Muestra la fuente de financiamiento declarada en la publicación.

Agradecimientos



Agradecimiento
This research was partly funded by the PBCT-PDA07 project granted by CONICYT (Chilean National Commission for Science and Technology). Additional support was provided by MECESUP doctoral fellowship (UCH-0708) and by FONDAP Proyect #15090013 "Centro de Excelencia en Geotermia de los Andes, CEGA". The authors acknowledge the additional support provided by the University of Florence (Laboratory of Fluid and Rock Geochemistry, Department of Earth Sciences and CNR-IGG). Careful and thoughtful suggestions of Y. Taran and J. Varekamp were warmly appreciated.
Acknowledgments This research was partly funded by the PBCT-PDA07 project granted by CONICYT (Chilean National Commission for Science and Technology). Additional support was provided by MECESUP doctoral fellowship (UCH-0708) and by FONDAP Proyect #15090013 “Centro de Excelencia en Geotermia de los Andes, CEGA”. The authors acknowledge the additional support provided by the University of Florence (Laboratory of Fluid and Rock Geochemistry, Department of Earth Sciences and CNR-IGG). Careful and thoughtful suggestions of Y. Taran and J. Varekamp were warmly appreciated.

Muestra la fuente de financiamiento declarada en la publicación.