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| DOI | 10.1007/S00445-013-0746-X | ||||
| Año | 2013 | ||||
| Tipo | artículo de investigación |
Citas Totales
Autores Afiliación Chile
Instituciones Chile
% Participación
Internacional
Autores
Afiliación Extranjera
Instituciones
Extranjeras
Tupungatito is a poorly known volcano located about 100 km eastward of Santiago (Chile) in the northernmost sector of the South Volcanic Zone. This 5,682 m high volcano shows intense fumarolic activity. It hosts three crater lakes within the northwestern portion of the summit area. Chemical compositions of fumarolic gases and isotopic signatures of noble gases (He-3/He-4 and Ar-40/Ar-36 are up to 6.09 Ra and 461, respectively), and steam (delta O-18 and delta D) suggest that they are produced by mixing of fluids from a magmatic source rich in acidic gas compounds (SO2, HCl, and HF), and meteoric water. The magmatic-hydrothermal fluids are affected by steam condensation that controls the outlet fumarolic temperatures (<83.6 degrees C), the gas chemical composition, and the steam isotopic values. The delta C-13-CO2 values (ranging from 0.30 and -8.16% vs. V-PDB) suggest that CO2 mainly derives from (1) a mantle source likely affected by significant contamination from the subducting slab, (2) the sedimentary basement, and (3) limited contribution from crustal sediments. Gas geothermometry based on the kinetically rapid H-2-CO equilibria indicates equilibrium temperatures <200 degrees C attained in a single vapor phase at redox conditions slightly more oxidizing than those commonly characterizing hydrothermal reservoirs. Reactions in the H2O-CO2-H-2-CO-CH4 system and C-2-C-3 alkenes/alkanes pairs, which have relatively slow kinetics, seem to equilibrate at greater depth, where temperatures are > 200 degrees C and redox conditions are consistent with those inferred by the presence of the SO2-H2S redox pair, typical of fluids that have attained equilibrium in magmatic environment. A comprehensive conceptual geochemical model describing the circulation pattern of the Tupungatito hydrothermal-magmatic fluids is proposed. It includes fluid source regions and re-equilibration processes affecting the different gas species due to changing chemical-physical conditions as the magmatic-hydrothermal fluids rise up toward the surface.
| Ord. | Autor | Género | Institución - País |
|---|---|---|---|
| 1 | BENAVENTE-ZOLEZZI, OSCAR MATIAS | Hombre |
Universidad de Chile - Chile
Centro de Excelencia en Geotermia de Los Andes - Chile |
| 2 | Tassi, Franco | Hombre |
UNIV FLORENCE - Italia
Università degli Studi di Firenze - Italia |
| 3 | GUTIERREZ-FERRER, FRANCISCO JAVIER | Hombre |
Universidad de Chile - Chile
Centro de Excelencia en Geotermia de Los Andes - Chile |
| 4 | Vaselli, O. | Hombre |
UNIV FLORENCE - Italia
Università degli Studi di Firenze - Italia |
| 5 | AGUILERA-VALENZUELA, FELIPE IGNACIO | Hombre |
Universidad de Chile - Chile
Universidad de Atacama - Chile Centro de Excelencia en Geotermia de Los Andes - Chile |
| 6 | REICH-MORALES, MARTIN HERBERT | Hombre |
Universidad de Chile - Chile
Centro de Excelencia en Geotermia de Los Andes - Chile |
| Fuente |
|---|
| FONDAP |
| MECESUP |
| Comisión Nacional de Investigación Científica y Tecnológica |
| Comisión Nacional de Investigación CientÃfica y Tecnológica |
| Fondo de Financiamiento de Centros de Investigación en Áreas Prioritarias |
| MECESUP Doctoral Fellowship |
| Chilean National Commission for Science and Technology |
| CONICYT (Chilean National Commission for Science and Technology) |
| University of Florence |
| FONDAP Proyect |
| PBCT-PDA07 project |
| Agradecimiento |
|---|
| This research was partly funded by the PBCT-PDA07 project granted by CONICYT (Chilean National Commission for Science and Technology). Additional support was provided by MECESUP doctoral fellowship (UCH-0708) and by FONDAP Proyect #15090013 "Centro de Excelencia en Geotermia de los Andes, CEGA". The authors acknowledge the additional support provided by the University of Florence (Laboratory of Fluid and Rock Geochemistry, Department of Earth Sciences and CNR-IGG). Careful and thoughtful suggestions of Y. Taran and J. Varekamp were warmly appreciated. |
| Acknowledgments This research was partly funded by the PBCT-PDA07 project granted by CONICYT (Chilean National Commission for Science and Technology). Additional support was provided by MECESUP doctoral fellowship (UCH-0708) and by FONDAP Proyect #15090013 “Centro de Excelencia en Geotermia de los Andes, CEGA”. The authors acknowledge the additional support provided by the University of Florence (Laboratory of Fluid and Rock Geochemistry, Department of Earth Sciences and CNR-IGG). Careful and thoughtful suggestions of Y. Taran and J. Varekamp were warmly appreciated. |