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| DOI | 10.1016/S1004-9541(13)60575-3 | ||||
| Año | 2013 | ||||
| Tipo | artículo de investigación |
Citas Totales
Autores Afiliación Chile
Instituciones Chile
% Participación
Internacional
Autores
Afiliación Extranjera
Instituciones
Extranjeras
Phase equilibrium in binary gas + water mixtures over wide ranges of temperatures and pressures are modeled and tested for thermodynamic consistency. For modeling, the Peng-Robinson equation of state was used and the Wong-Sandler mixing rules were incorporated into the equation of state parameters. In the Wong-Sandler mixing rules the van Laar model for the excess Gibbs energy was applied. In addition, a reasonable and flexible method is applied to test the thermodynamic consistency of pressure-temperature-concentration (P-T-x) data of these binary mixtures. Modeling is found acceptable in all cases, meaning that deviations in correlating the pressure and the gas phase concentration are low. For all cases the thermodynamic consistency method gives a clear conclusion about consistency or inconsistency of a set of experimental P-T-x data.
| Ord. | Autor | Género | Institución - País |
|---|---|---|---|
| 1 | FAUNDEZ-ARAYA, CLAUDIO ALONSO | Hombre |
Universidad de Concepción - Chile
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| 2 | Quiero, Felipe | Hombre |
Universidad Nacional Andrés Bello - Chile
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| 3 | VALDERRAMA-MENDEZ, JOSE OMAR | Hombre |
Universidad de la Serena - Chile
Centro de Informacion Tecnologica - Chile Center for Technological Information - Chile |
| Fuente |
|---|
| CONICYT |
| DIUC |
| University of La Serena |
| National Council for Scientific and Technological Research |
| Center for Technological Information (La Serena-Chile) |
| Agradecimiento |
|---|
| The authors thank the National Council for Scientific and Technological Research, CONICYT, for its grant FONDECYT 3020020 and the Center for Technological Information (La Serena-Chile) for computer and library support. CAF thanks the Direction of Research of the University of Concepcicn for the support through the research grant DIUC 211.011.054-1.0. JOV thanks the University of La Serena for especial support. |