This paper is devoted to photometric study of the Galactic globular cluster (GGC) NGC 6752 in UBVI, focusing on the multiplicity of its stellar population. We emphasize that our U passband is (1) narrower than the standard one due to its smaller extension blueward and (2) redshifted by similar to 300 angstrom relative to its counterparts, such as the HST F336W filter. Accordingly, both the spectral features encompassed by it and photometric effects of the multiplicity revealed in our study are somewhat different than in recent studies of NGC 6752. Main sequence stars bluer in U - B are less centrally concentrated, as red giants are. We find a statistically significant increasing luminosity of the red giant branch (RGB) bump of.Delta U approximate to 0.2 mag toward the cluster outskirts with no so obvious effect in V. The photometric results are correlated with spectroscopic data: the bluer RGB stars in U - B have lower nitrogen abundances. We draw attention to a larger width of the RGB than the blue horizontal branch (BHB) in U - B. This seems to agree with the effects predicted to be caused by molecular bands produced by nitrogen-containing molecules. We find that brighter BHB stars, especially the brightest ones, are more centrally concentrated. This implies that red giants that are redder in U - B, i.e., more nitrogen enriched and centrally concentrated, are the main progenitors of the brighter BHB stars. However, such a progenitor-progeny relationship disagrees with theoretical predictions and with the results on the elemental abundances in horizontal branch stars. We isolated the asymptotic giant branch clump and estimated the parameter clump Delta V-ZAHB(clump) = 0.98 +/- 0.12.