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| Indexado |
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| DOI | 10.1002/2014JD021698 | ||
| Año | 2014 | ||
| Tipo | artículo de investigación |
Citas Totales
Autores Afiliación Chile
Instituciones Chile
% Participación
Internacional
Autores
Afiliación Extranjera
Instituciones
Extranjeras
Variability in the chemistry of the upper stratosphere/lowermesosphere region has been analyzed focusing on high latitudes during the boreal winter in 2009 characterized by the strong sudden stratospheric warming (SSW) on 24 January. Data from Michelson Interferometer for Passive Atmospheric Sounding aboard Envisat and the Microwave Limb Sounder on Aura have been used to exemplify these changes. Record high (low) values of O-3 and ClO (temperature and HCl) for the winters of 2005-2012, coupled with a simultaneous enhancement of ClONO2, have been observed in February 2009. This suggests that the very low temperatures favor a more effective ozone production and a greater O-3/O ratio. The latter is the main factor controlling active chlorine partitioning. Increases of ClO lead to high ClONO2 concentrations in the upper stratosphere at high latitudes, where its photodissociation rate is smaller. Since this increase of ClONO2 happens at the expense of HCl, the region of high ClONO2 roughly coincides with the region of low HCl. Although this period was characterized by an elevated stratopause event, the investigated region was not influenced by the descent of mesospheric air rich in NOx. Some limited enhancements in NOx at similar to 1 hPa occurred at latitudes greater than 80 degrees N after about 20 February, but they became consistent only in March. Intrusion of midlatitude air mostly occurred between the SSW and early February. Then, the sum of volume mixing ratios of ClONO2 + ClO + HCl remained approximately constant and close to the values of the other years. In contrast, it was up to 0.2 ppbv lower during the SSW period. These atypical chemical conditions occurred also in February 2006, but 2009 stands out for its long-lasting effects, which persisted until late March.
| Ord. | Autor | Género | Institución - País |
|---|---|---|---|
| 1 | Damiani, Alessandro | Hombre |
Universidad de Santiago de Chile - Chile
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| 2 | Funke, Bernd | Hombre |
CSIC - España
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| 3 | Lopez-Puertas, Manuel | Hombre |
CSIC - España
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| 4 | Gardini, Angela | Mujer |
CSIC - España
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| 5 | von Clarmann, Thomas | Hombre |
Karlsruhe Inst Technol - Alemania
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| 6 | Santee, Michelle L. | - |
CALTECH - Estados Unidos
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| 7 | Froidevaux, Lucien | - |
CALTECH - Estados Unidos
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| 8 | CORDERO-CARRASCO, RAUL RODRIGO | Hombre |
Universidad de Santiago de Chile - Chile
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| Fuente |
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| FONDECYT |
| Fondef |
| NASA |
| SOUSEI program, MEXT, JAPAN |
| USACH-DICYT |
| EC FEDER |
| Spanish MCINN |
| Agradecimiento |
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| The support of USACH-DICYT, FONDEF (IT13110034), and FONDECYT (1140239) is gratefully acknowledged. A.D. was also supported by the SOUSEI program, MEXT, JAPAN. Work at the Jet Propulsion Laboratory, California Institute of Technology, was done under contract with NASA. The IAA team was supported by the Spanish MCINN under grant AYA2011-23552 and EC FEDER funds. IMK/IAA-generated MIPAS/Envisat data can be obtained by registered users from the data server: http://www.imk-asf.kit.edu/english/308.php. MLS/Aura data are available at the Jet Propulsion Laboratory MLS website: http://mls.jpl.nasa.gov/index.php. |