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| DOI | 10.1016/J.COLSURFA.2015.06.036 | ||||
| Año | 2015 | ||||
| Tipo | artículo de investigación |
Citas Totales
Autores Afiliación Chile
Instituciones Chile
% Participación
Internacional
Autores
Afiliación Extranjera
Instituciones
Extranjeras
A new empirical three-parameter viscoelastic model is proposed for describing the rheological behavior of linear and nonlinear materials. In particular, the model succesfully reproduced experimental creep curves at various constant stresses for flocculated suspensions of alumina in the presence of different types of seawater salts. The new model is compared to the classical standard linear solid model and to an extension of this, also proposed here, to represent nonlinear materials. Based on the goodness of fit, the new model is found to be the most appropriate for the experimental system studied. A sensitivity analysis of the parameters to applied stress and type of salt in the sediments reveals that the new model, originally proposed as an ansatz, has three components, constant, linear and nonlinear, as inferred from the behaviour of each model parameter with the applied stresses. The linear contribution follows a correlation with the applied stresses for salts that enhance the hydrogen network of water, so called maker salts, and another for the salts that weaken the network, so called breaker salts. Even more interesting, the nonlinear contribution is characterized by large exponential decay lengths for breaker salts and small exponential decay lengths for maker salts. The existence of linear and nonlinear components may enable applying the model to a variety of systems. (C) 2015 Elsevier B.V. All rights reserved.
| Ord. | Autor | Género | Institución - País |
|---|---|---|---|
| 1 | Goni, Christian | Hombre |
Universidad de Concepción - Chile
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| 2 | JELDRES-VALENZUELA, RICARDO IVAN | Mujer |
Universidad de Concepción - Chile
Csirochile Int Ctr Excellence - Chile CSIRO-Chile International Center of Excellence in Mining and Mineral Processing - Chile The University of Queensland - Australia |
| 3 | TOLEDO-RAMIREZ, PEDRO GONZALO | Hombre |
Universidad de Concepción - Chile
|
| 4 | Stickland, Anthony D. | Hombre |
Univ Melbourne - Australia
University of Melbourne - Australia |
| 5 | Scales, Peter J. | Hombre |
Univ Melbourne - Australia
University of Melbourne - Australia |
| Fuente |
|---|
| CONICYT-Chile |
| Australian Research Council |
| University of Melbourne |
| Ministerio de Educacion, Gobierno de Chile |
| Ministerio de Educación, Gobierno de Chile |
| CRHIAM Conicyt/Fondap Project |
| Red Doctoral REDOC.CTA, MINEDUC Grant |
| Agradecimiento |
|---|
| RIJ thanks CONICYT-Chile for a graduate student fellowship and a research internship at the Department of Chemical and Biomolecular Engineering, The University of Melbourne, Australia, where the experimental work was carried out. We thank the support of CRHIAM Conicyt/Fondap Project-15130015 and Red Doctoral REDOC.CTA, MINEDUC Grant # UCO1202. The infrastructure support of the Particulate Fluids Processing Centre, a Special Research Centre of the Australian Research Council, is gratefully acknowledged. |
| RIJ thanks CONICYT-Chile for a graduate student fellowship and a research internship at the Department of Chemical and Biomolecular Engineering, The University of Melbourne, Australia, where the experimental work was carried out. We thank the support of CRHIAM Conicyt/Fondap Project-15130015 and Red Doctoral REDOC.CTA, MINEDUC Grant # UCO1202. The infrastructure support of the Particulate Fluids Processing Centre, a Special Research Centre of the Australian Research Council, is gratefully acknowledged. |