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A non-linear viscoelastic model for sediments flocculated in the presence of seawater salts
Indexado
WoS WOS:000360411300060
Scopus SCOPUS_ID:84937239411
DOI 10.1016/J.COLSURFA.2015.06.036
Año 2015
Tipo artículo de investigación

Citas Totales

Autores Afiliación Chile

Instituciones Chile

% Participación
Internacional

Autores
Afiliación Extranjera

Instituciones
Extranjeras


Abstract



A new empirical three-parameter viscoelastic model is proposed for describing the rheological behavior of linear and nonlinear materials. In particular, the model succesfully reproduced experimental creep curves at various constant stresses for flocculated suspensions of alumina in the presence of different types of seawater salts. The new model is compared to the classical standard linear solid model and to an extension of this, also proposed here, to represent nonlinear materials. Based on the goodness of fit, the new model is found to be the most appropriate for the experimental system studied. A sensitivity analysis of the parameters to applied stress and type of salt in the sediments reveals that the new model, originally proposed as an ansatz, has three components, constant, linear and nonlinear, as inferred from the behaviour of each model parameter with the applied stresses. The linear contribution follows a correlation with the applied stresses for salts that enhance the hydrogen network of water, so called maker salts, and another for the salts that weaken the network, so called breaker salts. Even more interesting, the nonlinear contribution is characterized by large exponential decay lengths for breaker salts and small exponential decay lengths for maker salts. The existence of linear and nonlinear components may enable applying the model to a variety of systems. (C) 2015 Elsevier B.V. All rights reserved.

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Disciplinas de Investigación



WOS
Chemistry, Physical
Scopus
Colloid And Surface Chemistry
Physical And Theoretical Chemistry
Surfaces And Interfaces
SciELO
Sin Disciplinas

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Publicaciones WoS (Ediciones: ISSHP, ISTP, AHCI, SSCI, SCI), Scopus, SciELO Chile.

Colaboración Institucional



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Autores - Afiliación



Ord. Autor Género Institución - País
1 Goni, Christian Hombre Universidad de Concepción - Chile
2 JELDRES-VALENZUELA, RICARDO IVAN Mujer Universidad de Concepción - Chile
Csirochile Int Ctr Excellence - Chile
CSIRO-Chile International Center of Excellence in Mining and Mineral Processing - Chile
The University of Queensland - Australia
3 TOLEDO-RAMIREZ, PEDRO GONZALO Hombre Universidad de Concepción - Chile
4 Stickland, Anthony D. Hombre Univ Melbourne - Australia
University of Melbourne - Australia
5 Scales, Peter J. Hombre Univ Melbourne - Australia
University of Melbourne - Australia

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Origen de Citas Identificadas



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Citas identificadas: Las citas provienen de documentos incluidos en la base de datos de DATACIENCIA

Citas Identificadas: 66.67 %
Citas No-identificadas: 33.33 %

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Citas identificadas: Las citas provienen de documentos incluidos en la base de datos de DATACIENCIA

Citas Identificadas: 66.67 %
Citas No-identificadas: 33.33 %

Financiamiento



Fuente
CONICYT-Chile
Australian Research Council
University of Melbourne
Ministerio de Educacion, Gobierno de Chile
Ministerio de Educación, Gobierno de Chile
CRHIAM Conicyt/Fondap Project
Red Doctoral REDOC.CTA, MINEDUC Grant

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Agradecimientos



Agradecimiento
RIJ thanks CONICYT-Chile for a graduate student fellowship and a research internship at the Department of Chemical and Biomolecular Engineering, The University of Melbourne, Australia, where the experimental work was carried out. We thank the support of CRHIAM Conicyt/Fondap Project-15130015 and Red Doctoral REDOC.CTA, MINEDUC Grant # UCO1202. The infrastructure support of the Particulate Fluids Processing Centre, a Special Research Centre of the Australian Research Council, is gratefully acknowledged.
RIJ thanks CONICYT-Chile for a graduate student fellowship and a research internship at the Department of Chemical and Biomolecular Engineering, The University of Melbourne, Australia, where the experimental work was carried out. We thank the support of CRHIAM Conicyt/Fondap Project-15130015 and Red Doctoral REDOC.CTA, MINEDUC Grant # UCO1202. The infrastructure support of the Particulate Fluids Processing Centre, a Special Research Centre of the Australian Research Council, is gratefully acknowledged.

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