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| Indexado |
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| DOI | 10.1002/MAME.201500380 | ||||
| Año | 2016 | ||||
| Tipo | artículo de investigación |
Citas Totales
Autores Afiliación Chile
Instituciones Chile
% Participación
Internacional
Autores
Afiliación Extranjera
Instituciones
Extranjeras
Different carbon-based fillers such as carbon nanotubes (CNTs), graphite, and thermally reduced graphene oxide (TrGO) are melt mixed with an isotactic poly(propylene) (iPP) and the mechanical properties of the resulting composites in the solid and melt state are analyzed. The Young's modulus of composites is increased around 25% relative to the neat iPP at concentrations above 10 wt% of CNTs or graphite whereas composites with TrGO are increased around 40% at similar concentrations. These results are compared with theoretical models showing that the filler agglomeration and surface area are key parameters. The rheological results of the composites under oscillatory shear conditions at the melt state show that the viscous raw polymer melt experiences a solid-like transition at a threshold concentration that strongly depends on the filler used. This transition appears at 10 wt% for CNTs, 8 wt% for TrGO, and 40 wt% for graphite. The viscosity of iPP/TrGO composites is further increased by adding CNTs particles, although the Young's modulus does not increase.
| Ord. | Autor | Género | Institución - País |
|---|---|---|---|
| 1 | GARZON, CRISTHIAN ANDRES | - |
Universidad de Chile - Chile
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| 2 | Wilhelm, Manfred | Hombre |
Karlsruhe Inst Technol - Alemania
Karlsruhe Institute of Technology - Alemania Karlsruher Institut für Technologie - Alemania |
| 3 | Abbasi, Mahdi | Hombre |
Karlsruhe Inst Technol - Alemania
Karlsruhe Institute of Technology - Alemania Karlsruher Institut für Technologie - Alemania |
| 4 | PALZA-CORDERO, HUMBERTO CRISTIAN | Hombre |
Universidad de Chile - Chile
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| Fuente |
|---|
| Consejo Nacional de Innovacion, Ciencia y Tecnologia |
| Comisi?n Nacional de Investigaci?n Cient?fica y Tecnol?gica |
| Korea Institute of Toxicology |
| Karlsruher Institut für Technologie |
| Comision Nacional de Investigacion Cientifica y Tecnologica (CONICYT)-Chile |
| project FODECYT |
| Electrical Testing Unit |
| Institut f?r Technische Chemie und Polymerchemie |
| Agradecimiento |
|---|
| The authors gratefully acknowledge the Comision Nacional de Investigacion Cientifica y Tecnologica (CONICYT)-Chile for the doctoral fellowship and project FODECYT 1150130. The authors also expressed thanks to E.E. Mario Vergara, Chief of the Electrical Testing Unit (IDIEM)-Chile. The authors are also thankful to all persons of the Institut fur Technische Chemie und Polymerchemie, Karlsruhe Institute of Technology (KIT), for the hospitality and collaboration provided during this investigation. |
| The authors gratefully acknowledge the Comisi?n Nacional de Investigaci?n Cient?fica y Tecnol?gica (CONICYT)-Chile for the doctoral fellowship and project FODECYT 1150130. The authors also expressed thanks to E.E. Mario Vergara, Chief of the Electrical Testing Unit (IDIEM)-Chile. The authors are also thankful to all persons of the Institut f?r Technische Chemie und Polymerchemie, Karlsruhe Institute of Technology (KIT), for the hospitality and collaboration provided during this investigation. |