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| DOI | 10.1016/J.CRCI.2016.02.002 | ||||
| Año | 2016 | ||||
| Tipo | artículo de investigación |
Citas Totales
Autores Afiliación Chile
Instituciones Chile
% Participación
Internacional
Autores
Afiliación Extranjera
Instituciones
Extranjeras
The application of the concept of chemical homology to describe melting properties of molten salts and ionic liquids (ILs) is analyzed. This concept was used several years ago to correlate and predict properties of solids and more recently to correlate melting temperatures of ILs. To analyze the characteristics of the extended method, this is first applied to melting properties of organic substances for which abundant data are available. The method is extended to analyze its applicability for properties of molten salts and ILs such as glass transition temperature, heat of melting, and entropy of melting. The foundation of the chemical homology concept is revised, and the difficulties for extending the method to correlate and predict melting properties of ILs are presented. Despite the difficulties, the homology concept can still be used with some conditions and limitations that are analyzed in this article. Several correlations are proposed. (C) 2016 Academie des sciences. Published by Elsevier Masson SAS. All rights reserved.
| Ord. | Autor | Género | Institución - País |
|---|---|---|---|
| 1 | VALDERRAMA-MENDEZ, JOSE OMAR | Hombre |
Universidad de la Serena - Chile
Centro de Informacion Tecnologica - Chile Center for Technological Information (CIT) - Chile |
| 2 | Campusano, Richard A. | Hombre |
Universidad de la Serena - Chile
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| Fuente |
|---|
| Conselho Nacional de Desenvolvimento Científico e Tecnológico |
| Fondo Nacional de Desarrollo Científico y Tecnológico |
| Comisión Nacional de Investigación Científica y Tecnológica |
| Comisión Nacional de Investigación CientÃfica y Tecnológica |
| Fondo Nacional de Desarrollo CientÃfico y Tecnológico |
| National Council for Scientific and Technological Research (CONICYT) |
| Consejo Nacional para Investigaciones CientÃficas y Tecnológicas |
| University of La Serena |
| Direction of Research of the University of La Serena |
| Direction of Research of the University of La Serena |
| Center for Technological Information of La Serena |
| Agradecimiento |
|---|
| This work was supported by the National Council for Scientific and Technological Research (CONICYT), through the research grant FONDECYT 1120162. The authors thank the Center for Technological Information of La Serena, Chile, for computer support and the Direction of Research of the University of La Serena for permanent support and for an especial graduate fellowship for one of the authors (R.A.C.). |
| This work was supported by the National Council for Scientific and Technological Research (CONICYT) , through the research grant FONDECYT 1120162 . The authors thank the Center for Technological Information of La Serena, Chile, for computer support and the Direction of Research of the University of La Serena for permanent support and for an especial graduate fellowship for one of the authors (R.A.C.). |