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Geochemical characterization of two distinctive systems with evidence of chemosynthetic activity, explored at the SE Pacific margin off Chile (46°S and 33°S)
Indexado
WoS WOS:000387524100002
Scopus SCOPUS_ID:84990246412
DOI 10.1016/J.POCEAN.2016.09.002
Año 2016
Tipo artículo de investigación

Citas Totales

Autores Afiliación Chile

Instituciones Chile

% Participación
Internacional

Autores
Afiliación Extranjera

Instituciones
Extranjeras


Abstract



Pore water from short cores was analyzed for dissolved major, minor, and trace elements (Cl, Na, Mg, K, Ca, Sr, Si, B, P, Ba, Pb, Mn, Fe, Cd, U, and Mo), delta(DIC)-D-13, sulfide, sulfate, and methane. The solid sediment fraction was likewise analyzed for total organic carbon (TOC), metals, and redox potential. Elevated sediment temperatures were found in superficial sediments (5-13 degrees C) at the CTJ site, which could be due to warm fluids associated with the proximity of the ridge, where hydrothermal vents may occur. Reduced fluids were also present here, indicated by higher Mn fluxes toward the water column even in oxidized sediments (RPD > 8 cm), which contrasted with the lower fluxes in reduced sediments of the EQSS site (RPD similar to 2 cm). C-13-depleted DIC, anomalously low pore water Cl (similar to 15 ppb), and low concentrations of other major elements may be the result of dilution by fluid seeping and precipitation of major elements, producing authigenic enrichment (Ca, Mg, Sr). The fluid could also: (a) be diluted by pure water produced during methane hydrate dissociation, as observed in other cold-seep areas; and (b) correspond to clay mineral dehydration, as reported in plate subduction systems. The reducing conditions established at the CTJ conduct the Cd enrichment at a similar magnitude of that seen at the shallower suboxic site (EQSS). Evidence of chimney or vent fauna was not observed. At the EQSS, higher TOC and total sulfide contents were consistent with enhanced deposition of organic matter and reducing conditions developed in the OMZ, favoring the authigenic enrichment of Cd, U and Pb. The geochemical evidence, based only on methane concentrations and delta(DIC)-D-13, is insufficient to establish the presence of methane seeps, as previously reported. (C) 2016 Elsevier Ltd. All rights reserved.

Revista



Revista ISSN
Progress In Oceanography 0079-6611

Métricas Externas



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Disciplinas de Investigación



WOS
Oceanography
Scopus
Geology
Aquatic Science
SciELO
Sin Disciplinas

Muestra la distribución de disciplinas para esta publicación.

Publicaciones WoS (Ediciones: ISSHP, ISTP, AHCI, SSCI, SCI), Scopus, SciELO Chile.

Colaboración Institucional



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Autores - Afiliación



Ord. Autor Género Institución - País
1 MUNOZ-PARRA, PRAXEDES NATALIA VIRGINIA Mujer Universidad Católica del Norte - Chile
Centro de Estudios Avanzados en Zonas Aridas - Chile
2 CARDENAS-HINOJOSA, LISSETTE JANINA Mujer Universidad Católica del Norte - Chile
3 Garbe-Schoenberg, D. Hombre Christian Albrechts Univ Kiel - Alemania
Christian-Albrechts-Universität zu Kiel - Alemania
4 SELLANES-LOPEZ, ROGELIO JAVIER Hombre Universidad Católica del Norte - Chile
5 Dezileau, Laurent Hombre Univ Montpellier 2 - Francia
Géosciences Montpellier - Francia
6 Melville, Ives Hombre Universidad Católica del Norte - Chile
7 Mendes, Stephanie D. Mujer UC Santa Barbara - Estados Unidos
University of California, Santa Barbara - Estados Unidos

Muestra la afiliación y género (detectado) para los co-autores de la publicación.

Financiamiento



Fuente
Universidad de Concepción
FONDECYT
Fondo Nacional de Desarrollo Científico y Tecnológico
University of Concepción
Fondo Nacional de Desarrollo Científico, Tecnológico y de Innovación Tecnológica
COPAS center from the University of Concepcion
NOAA Ocean Exploration Program (via SCRIPPS Institution of Oceanography)
Census of Marine Life program (through its field project COMARGE)
NOAA Ocean Exploration Program

Muestra la fuente de financiamiento declarada en la publicación.

Agradecimientos



Agradecimiento
We would like to thank the captain and crew of the R/V MEL-VILLE, Scripps Institution of Oceanography, during the Inspire 2010 cruise. We also give thanks to Dr. Jesse Muratli and Dr. Sebastien Bertrand, for sharing unpublished data from river samples. This work was partially funded by the FONDECYT projects No. 1100166 and 1120469 (to J.S.), and the COPAS center from the University of Concepcion. Additional funding to P.M. during the writing phase of this manuscript was provided by FONDECYT project 1140851 for additional sediment sample analyzes. Other funding, for logistics and ship time, was provided by the NOAA Ocean Exploration Program (via SCRIPPS Institution of Oceanography, contract NOAA NA17RJ1231) and the Census of Marine Life program (through its field project COMARGE).
We would like to thank the captain and crew of the R/V MELVILLE, Scripps Institution of Oceanography, during the Inspire 2010 cruise. We also give thanks to Dr. Jesse Muratli and Dr. Sebastien Bertrand, for sharing unpublished data from river samples. This work was partially funded by the FONDECYT projects No. 1100166 and 1120469 (to J.S.), and the COPAS center from the University of Concepción . Additional funding to P.M. during the writing phase of this manuscript was provided by FONDECYT project 1140851 for additional sediment sample analyzes. Other funding, for logistics and ship time, was provided by the NOAA Ocean Exploration Program (via SCRIPPS Institution of Oceanography , contract NOAA NA17RJ1231 ) and the Census of Marine Life program (through its field project COMARGE).

Muestra la fuente de financiamiento declarada en la publicación.