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| DOI | 10.5194/ACP-17-6477-2017 | ||||
| Año | 2017 | ||||
| Tipo | artículo de investigación |
Citas Totales
Autores Afiliación Chile
Instituciones Chile
% Participación
Internacional
Autores
Afiliación Extranjera
Instituciones
Extranjeras
The knowledge of surface ozone mole fractions and their global distribution is of utmost importance due to the impact of ozone on human health and ecosystems and the central role of ozone in controlling the oxidation capacity of the troposphere. The availability of long-term ozone records is far better in the Northern than in the Southern Hemisphere, and recent analyses of the seven accessible records in the Southern Hemisphere have shown inconclusive trends. Since late 1995, surface ozone is measured in situ at "El Tololo", a high-altitude (2200ma.s.l.) and pristine station in Chile (30 degrees S, 71 degrees W). The dataset has been recently fully quality controlled and reprocessed. This study presents the observed ozone trends and annual cycles and identifies key processes driving these patterns. From 1995 to 2010, an overall positive trend of similar to 0.7 ppbdecade(-1) is found. Strongest trends per season are observed in March and April. Highest mole fractions are observed in late spring (October) and show a strong correlation with ozone transported from the stratosphere down into the troposphere, as simulated with a model. Over the 20 years of observations, the springtime ozone maximum has shifted to earlier times in the year, which, again, is strongly correlated with a temporal shift in the occurrence of the maximum of simulated stratospheric ozone transport at the site. We conclude that background ozone at El Tololo is mainly driven by stratospheric intrusions rather than photochemical production from anthropogenic and biogenic precursors. The major footprint of the sampled air masses is located over the Pacific Ocean. Therefore, due to the negligible influence of local processes, the ozone record also allows studying the influence of El Nino and La Nina episodes on background ozone levels in South America. In agreement with previous studies, we find that, during La Nina conditions, ozone mole fractions reach higher levels than during El Nino conditions.
| Ord. | Autor | Género | Institución - País |
|---|---|---|---|
| 1 | Anet, Julien G. | Hombre |
Swiss Fed Labs Mat Sci & Technol Empa - Suiza
WSL Inst Snow & Avalanche Res SLF - Suiza Empa - Swiss Federal Laboratories for Materials Science and Technology - Suiza |
| 1 | Anet, G. Julien | - |
Empa - Swiss Federal Laboratories for Materials Science and Technology - Suiza
WSL - Institut für Schnee- und Lawinenforschung SLF - Davos - Suiza |
| 2 | Steinbacher, Martin | Hombre |
Swiss Fed Labs Mat Sci & Technol Empa - Suiza
Empa - Swiss Federal Laboratories for Materials Science and Technology - Suiza |
| 3 | GALLARDO-KLENNER, LAURA ELEONOR | Mujer |
Universidad de Chile - Chile
Centro de Ciencia del Clima y la Resiliencia - Chile Center for Climate and Resilience Research - Chile Ctr Climate & Resilience Res CR2 - Chile Centro de Ciencia del Clima y la Resiliencia (CR)2 - Chile |
| 4 | ALVAREZ-MENDOZA, PATRICIO ALEJANDRO | Hombre |
Direcc Meteorol Chile - Chile
Univ Bern - Suiza University of Bern - Suiza |
| 4 | Velásquez Álvarez, A. Patricio | - |
Estación Central - Chile
University of Bern - Suiza |
| 5 | Emmenegger, Lukas | Hombre |
Swiss Fed Labs Mat Sci & Technol Empa - Suiza
Empa - Swiss Federal Laboratories for Materials Science and Technology - Suiza |
| 6 | Buchmann, Brigitte | Mujer |
Swiss Fed Labs Mat Sci & Technol Empa - Suiza
Empa - Swiss Federal Laboratories for Materials Science and Technology - Suiza |
| Fuente |
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| FONDAP |
| Swiss Agency for Development and Cooperation (SDC) |
| MeteoSwiss |
| Federal Office of Meteorology and Climatology MeteoSwiss through the project Capacity Building and Twinning for Climate Observing Systems (CATCOS) |
| Agradecimiento |
|---|
| We acknowledge the support of the Federal Office of Meteorology and Climatology MeteoSwiss through the project Capacity Building and Twinning for Climate Observing Systems (CATCOS) Phase 2, contract no. 81025332, between the Swiss Agency for Development and Cooperation (SDC) and MeteoSwiss. Moreover, we would like to express our gratitude towards Michael Sprenger and Bojan Skerlak, who both advised us how to use their ozone-STE climatology. As well, we thank Dr. Stephan Henne for his support concerning the FLEXTRA datasets and Dr. Dominik Brunner for his valuable comments. Laura Gallardo is grateful for the support of FONDAP 15110009. We would also like to thank the two anonymous reviewers and the editor, Jason West, for their detailed and helpful comments. |