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Currierite, Na4Ca3MgAl4(AsO3OH)(12)center dot 9H(2)O, a new acid arsenate with ferrinatrite-like heteropolyhedral chains from the Torrecillas mine, Iquique Province, Chile
Indexado
WoS WOS:000417989200009
Scopus SCOPUS_ID:85030152854
DOI 10.1180/MINMAG.2016.080.167
Año 2017
Tipo artículo de investigación

Citas Totales

Autores Afiliación Chile

Instituciones Chile

% Participación
Internacional

Autores
Afiliación Extranjera

Instituciones
Extranjeras


Abstract



The new mineral currierite (IMA2016-030), Na4Ca3MgAl4(AsO3OH)(12)center dot 9H(2)O, was found at the Torrecillas mine, Iquique Province, Chile, where it occurs as a secondary alteration phase in association with anhydrite, canutite, chudobaite, halite, lavendulan, magnesiokoritnigite, quartz, scorodite and torrecillasite. Currierite occurs as hexagonal prisms, needles and hair-like fibres up to similar to 200 mu m long, in sprays. The crystal forms are {100} and {001}. Crystals are transparent, with vitreous to silky lustre and white streak. The Mohs hardness is similar to 2, tenacity is brittle, but elastic in very thin fibres, and the fracture is irregular. Crystals exhibit at least one good cleavage parallel [001]. The measured density is 3.08(2) g cm(3) and the calculated density is 3.005 g cm(3). Optically, currierite is uniaxial () with omega = 1.614(1) and epsilon = 1.613(1) (measured in white light). The mineral is slowly soluble in dilute HCl at room temperature. The empirical formula, determined from electron-microprobe analyses, is (Na(3.95)Al(2.96)Ca(2.74)Mg(1.28)fe(0.63)(3+)Cu(0.13)K(0.08)Co(0.03))Sigma(11.80()AS(11.68)(5+)Sb(0.32)(5+) Sigma(12)(O56.96Cl0.04)Sigma H-57(30.81). Currierite is hexagonal, P622, with a = 12.2057(9), c = 9.2052(7) angstrom, V = 1187.7(2) angstrom(3) and Z = 1. The eight strongest powder X-ray diffraction lines are [d(obs) angstrom(I)(hkl)]: 10.63(100)(100), 6.12(20)(110), 5.30(15)(200), 4.61(24)(002), 4.002(35)(210), 3.474(29)(202), 3.021(96)(212) and 1.5227(29)(440,334,612). The structure of currierite (R-1 = 2.27% for 658 F-o > 4 sigma F reflections) is based upon a heteropolyhedral chain along c in which AlO6 octahedra are triple-linked by sharing corners with AsO3OH tetrahedra. Chains are linked to one another by bonds to 8(4 + 4)-coordinated Na and 8-coordinated Ca forming a three-dimensional framework with large cavities that contain rotationally disordered Mg(H2O)(6) octahedra. The chain in the structure of currierite is identical to that in kaatialaite and a geometrical isomer of that in ferrinatrite. The mineral is named in honour of Mr. Rock Henry Currier (19402015), American mineral dealer, collector, author and lecturer.

Revista



Revista ISSN
Mineralogical Magazine 0026-461X

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Disciplinas de Investigación



WOS
Mineralogy
Scopus
Geochemistry And Petrology
SciELO
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Publicaciones WoS (Ediciones: ISSHP, ISTP, AHCI, SSCI, SCI), Scopus, SciELO Chile.

Colaboración Institucional



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Autores - Afiliación



Ord. Autor Género Institución - País
1 Kampf, Anthony R. Hombre Nat Hist Museum Los Angeles Cty - Estados Unidos
Natural History Museum of Los Angeles County - Estados Unidos
2 Mills, Stuart J. J. Hombre Museum Victoria - Australia
3 Nash, Barbara P. P. Mujer Univ Utah - Estados Unidos
University of Utah - Estados Unidos
The University of Utah - Estados Unidos
4 Dini, Maurizio Hombre
5 Donoso, A. A. Molina Hombre

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Citas identificadas: Las citas provienen de documentos incluidos en la base de datos de DATACIENCIA

Citas Identificadas: 33.33 %
Citas No-identificadas: 66.67 %

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Citas identificadas: Las citas provienen de documentos incluidos en la base de datos de DATACIENCIA

Citas Identificadas: 33.33 %
Citas No-identificadas: 66.67 %

Financiamiento



Fuente
John Jago Trelawney Endowment
John Jago Trelawney Endowment to the Mineral Sciences Department of the Natural History Museum of Los Angeles County

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Agradecimientos



Agradecimiento
Editorial Board Member Andrew Christy, Structures Editor Peter Leverett and reviewer Francesco Demartin arc thanked for their constructive comments on the manuscript. A portion of this study was funded by the John Jago Trelawney Endowment to the Mineral Sciences Department of the Natural History Museum of Los Angeles County.
Editorial Board Member Andrew Christy, Structures Editor Peter Leverett and reviewer Francesco Demartin are thanked for their constructive comments on the manuscript. A portion of this study was funded by the John Jago Trelawney Endowment to the Mineral Sciences Department of the Natural History Museum of Los Angeles County.

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