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Facile one-step coating of thiol-ene polyHIPE with polydopamine, gold and palladium nanoparticles
Indexado
Scopus SCOPUS_ID:105008326155
DOI 10.1016/J.POLYMER.2025.128680
Año 2025
Tipo

Citas Totales

Autores Afiliación Chile

Instituciones Chile

% Participación
Internacional

Autores
Afiliación Extranjera

Instituciones
Extranjeras


Abstract



Porous emulsion-templated polymers (polyHIPEs) exhibit highly interconnected porosity and specific surface area, making them attractive for applications in tissue engineering, catalysis, water remediation, and energy storage. Noble metal nanoparticles, such as gold (AuNPs) and palladium nanoparticles (PdNPs), are widely used for their catalytic, electronic, and biomedical properties. However, conventional methods for incorporating these nanoparticles into polyHIPEs often require toxic reducing agents, multi-step procedures, and offer limited control over nanoparticle distribution. In this study, we report a facile one-step approach for preparing polydopamine (PDA)-coated polyHIPEs functionalised with AuNPs and PdNPs under mild basic conditions at room temperature. PDA serves as both a reducing agent and an adhesive layer, enabling uniform nanoparticle deposition while preventing aggregation. The process was conducted with four different concentrations of Au and Pd precursors, allowing controlled variation in nanoparticle density. The resulting material demonstrated high stability, well-distributed nanoparticles, and structural properties suitable for potential applications, in catalysis, sensing devices and tissue engineering. This environmentally friendly strategy provides a simple and scalable method for functionalizing porous polymers with noble metal nanoparticles, expanding the scope of polyHIPE-based materials for sustainable and biomedical applications.

Revista



Revista ISSN
Polymer 0032-3861

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Disciplinas de Investigación



WOS
Polymer Science
Scopus
Materials Chemistry
Polymers And Plastics
Organic Chemistry
SciELO
Sin Disciplinas

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Publicaciones WoS (Ediciones: ISSHP, ISTP, AHCI, SSCI, SCI), Scopus, SciELO Chile.

Colaboración Institucional



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Autores - Afiliación



Ord. Autor Género Institución - País
1 Naranjo Ruiz, Cintia - Pontificia Universidad Católica de Valparaíso - Chile
2 Cameron, Neil R. - Monash University - Australia
Faculty of Science, Engineering and Medicine - Reino Unido
Universiti Malaya - Malasia
3 Kimmins, Scott Hombre Pontificia Universidad Católica de Valparaíso - Chile

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Financiamiento



Fuente
Fondo Nacional de Desarrollo Científico y Tecnológico
European Commission
Pontificia Universidad Católica de Valparaíso
Australian Research Council
H2020 Marie Skłodowska-Curie Actions
CTET

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Agradecimientos



Agradecimiento
The authors acknowledge the use of facilities within the Monash X-ray Platform and the Monash Centre for Electron Microscopy. NRC acknowledges funding from the Australian Research Council for the Industrial Transformation Training Centre for Cell and Tissue Engineering Technologies (CTET) , grant number IC190100026 . The European Union is gratefully acknowledged for funding through the project SURE-Poly (Marie Sk\u0142odowska-Curie grant agreement No. 101085759 ). CNR acknowledges funding from PUCV Internal Scholarships.
ANID-Fondecyt (Chile) project no. 11190462.Beca ANID doctorado nacional (Chile) no. 21200236.The authors declare the following financial interests/personal relationships which may be considered as potential competing interests: Neil cameron reports financial support was provided by Australian Research Council. Scott Kimmins reports financial support was provided by ANID-Fondecyt (Chile). Scott Kimmins reports financial support was provided by Beca ANID doctorado nacional (Chile). Guest editor for the Polymer special issue on Porous Polymers (Neil Cameron) If there are other authors, they declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.The authors acknowledge the use of facilities within the Monash X-ray Platform and the Monash Centre for Electron Microscopy. NRC acknowledges funding from the Australian Research Council for the Industrial Transformation Training Centre for Cell and Tissue Engineering Technologies (CTET), grant number IC190100026. The European Union is gratefully acknowledged for funding through the project SURE-Poly (Marie Sk\u0142odowska-Curie grant agreement No. 101085759). CNR acknowledges funding from PUCV Internal Scholarships.

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