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Development of environment-friendly cardanol-derived hydrophobic anticorrosive high solid waterborne nano-dispersed polyurethane coatings
Indexado
WoS WOS:001504261300002
Scopus SCOPUS_ID:105006874575
DOI 10.1016/J.PORGCOAT.2025.109402
Año 2025
Tipo artículo de investigación

Citas Totales

Autores Afiliación Chile

Instituciones Chile

% Participación
Internacional

Autores
Afiliación Extranjera

Instituciones
Extranjeras


Abstract



This study presents a facile, clean route of fabrication of an eco-friendly, hydrophobic, and high solid (75.5 %) Cardanol-derived nano-dispersed waterborne polyurethane (WBPU) coatings to mitigate mild steel corrosion. The absence of additional crosslinkers and the use of green chemistry principles to develop WBPU nano-dispersions make the process feasible and environmentally benign. The impact of the variation in the amine content (10-25 %) was observed on the physical, chemical, and corrosive properties of the nano-dispersed WBPU coatings. FTIR analysis confirmed the chemical structure and curing of WBPU, while the crosslinking density indicated the formation of a protective coating surface. Transmission electron microscopy (TEM) analysis revealed the presence of uniform spherical nano-dispersions of size 7 +/- 3 nm. A strong correlation was observed between Dynamic light scattering and TEM analysis, confirming uniform nano-dispersion with long-term stability. X-ray diffraction and scanning electron microscopy analysis demonstrated an amorphous surface with dense and rough morphology, with spherical nanostructures. Atomic force microscopy studies reveal a surface with moderate nano-roughness with a balanced distribution of peaks and valleys. Physico-mechanical testing showed excellent performance across all compositions, with high scratch hardness (2 kg), impact resistance (passes 150 lb./in.), bending flexibility (passes 1/8 in.), 100 % crosshatch adhesion, gloss, and wear resistance. Chemical resistance (3.5 % HCl, NaCl, NaOH, ethyl methyl ketone, and water) showed no significant changes, confirming durability. Overall, the composition with 20 % amine exhibited superior performance, featuring high hydrophobicity and thermal stability up to 230 degrees C. Electrochemical impedance spectroscopy in 3.5 % NaCl for 24 days demonstrated exceptional corrosion inhibition efficiency (98.98 %), corrosion protection, low corrosion rates, and excellent barrier properties. Cardanol-based WBPU nano-dispersion coatings and their formulation offer a sustainable, high-performance alternative protective polymeric material for various applications.

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Disciplinas de Investigación



WOS
Chemistry, Applied
Materials Science, Coatings & Films
Scopus
Materials Chemistry
Chemical Engineering (All)
Surfaces, Coatings And Films
Organic Chemistry
SciELO
Sin Disciplinas

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Publicaciones WoS (Ediciones: ISSHP, ISTP, AHCI, SSCI, SCI), Scopus, SciELO Chile.

Colaboración Institucional



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Autores - Afiliación



Ord. Autor Género Institución - País
1 Sharma, Shiva - Jamia Millia Islamia - India
2 Zafar, Fahmina - Jamia Millia Islamia - India
3 Ghosal, Anujit - Red River Coll - Canadá
4 Singh, Paramjit - Jamia Millia Islamia - India
Universidad de Concepción - Chile
5 Jahan, Afroz - Jamia Millia Islamia - India
6 Alam, Manawwer - King Saud Univ - Arabia Saudí
College of Sciences - Arabia Saudí
7 Nishat, Nahid - Jamia Millia Islamia - India

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Financiamiento



Fuente
University Grants Commission
King Saud University
King Saud University, Riyadh, Saudi Arabia
Department of Science and Technology, India
Department of Science and Technology, Ministry of Science and Technology, India
University Grants Commission (UGC) , New Delhi, India
Ongoing Research Funding Program
DST-Women Scientist Scheme (WOS-A)

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Agradecimientos



Agradecimiento
Shiva Sharma gratefully acknowledges the University Grants Commission (UGC) , New Delhi, India, for the financial assistance from the Non Net fellowship for her doctoral research. Dr. Fahmina Zafar is thankful to the Department of Science and Technology, India, for their support under the DST-Women Scientist Scheme (WOS-A) (Ref# DST/WOS-A/CS-83/2021) . Prof. Manawwer Alam is thankful to the Ongoing Research Funding Program (ORF-2025-113) , King Saud University, Riyadh, Saudi Arabia. The authors also sincerely thank the Head of the Department of Chemistry for providing the necessary facilities to carry out this work.
Shiva Sharma gratefully acknowledges the University Grants Commission (UGC), New Delhi, India , for the financial assistance from the Non Net fellowship for her doctoral research. Dr. Fahmina Zafar is thankful to the Department of Science and Technology, India , for their support under the DST-Women Scientist Scheme (WOS-A) (Ref# DST/WOS-A/CS-83/2021 ). Prof. Manawwer Alam is thankful to the Ongoing Research Funding Program ( ORF-2025-113 ), King Saud University, Riyadh, Saudi Arabia. The authors also sincerely thank the Head of the Department of Chemistry for providing the necessary facilities to carry out this work.

Muestra la fuente de financiamiento declarada en la publicación.