This research determines how to integrate factors related to evacuation in emergency preparedness using techniques for Multicriteria Decision-Making (MCDM). A distinctive MCDM technique that incorporates human behavior into evacuation models enhances decision-making and safety during emergencies, especially in vulnerable populations. For this purpose, a hybrid combination of MCDM methods-CRiteria Importance Through Intercriteria Correlation (CRITIC), Technique for Order of Preference by Similarity to Ideal Solution (TOPSIS), and Weighted Aggregated Sum Product Assessment (WASPAS)-is used to rank the vulnerability of Chilean regions by considering various factors. First, the related factors are ranked by CRITIC, and the result is that the "psychosocial problem" factor has the highest priority and weight. Then, according to the hybrid methods and CRITIC, all regions of Chile are ranked first with TOPSIS, WASPAS, and a combination of them to determine which one has the highest priority. The results show that the Santiago Metropolitan Region has the highest priority for vulnerability in all three methods.