In this work, we construct novel asymptotically locally AdS5\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$_5$$\end{document} black hole solutions of Einstein-Gauss-Bonnet theory at the Chern-Simons point, supported by a scalar field that generates a primary hair. The strength of the scalar field is governed by an independent integration constant; when this constant vanishes, the spacetime reduces to a black hole geometry devoid of hair. The existence of these solutions is intrinsically tied to the horizon metric, which is modeled by three non-trivial Thurston geometries: Nil, Solv, and SL(2,R).\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$SL(2,{\mathbb {R}}).$$\end{document} The quadratic part of the scalar field action corresponds to a conformally coupled scalar in five dimensions -an invariance of the matter sector that is explicitly broken by the introduction of a quartic self-interaction. These black holes are characterized by two distinct parameters: the horizon radius and the temperature. Notably, there exists a straight line in this parameter space along which the horizon geometry exhibits enhanced isometries, corresponding to solutions previously reported in JHEP 02, 014 (2014). Away from this line, for a fixed horizon radius and temperatures above or below a critical value, the metric's isometries undergo spontaneous breaking. Employing the Regge-Teitelboim approach, we compute the mass and entropy of these solutions, both of which vanish. Despite this, only one of the integration constants can be interpreted as hair, as the other modifies the local geometry at the conformal boundary. Finally, for Solv horizon geometries, we extend these hairy solutions to six dimensions.