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MXene-enhanced nanofluids for superior thermal energy storage in concentrated solar power plants
Indexado
WoS WOS:001419682900001
Scopus SCOPUS_ID:85216636654
DOI 10.1016/J.SOLMAT.2025.113461
Año 2025
Tipo artículo de investigación

Citas Totales

Autores Afiliación Chile

Instituciones Chile

% Participación
Internacional

Autores
Afiliación Extranjera

Instituciones
Extranjeras


Abstract



The development and optimization of concentrated solar power plants (CSP) plants, which are considered promising sources of renewable and clean energy, have attracted significant attention. Recently, efforts to improve the efficiency of these plants have focused on increasing their operational temperature. However, this approach presents challenges, particularly regarding the corrosion of metallic components due to the higher temperatures of the molten salts used for energy storage. One potential solution to enhance the thermophysical properties of molten salts and mitigate corrosion is the incorporation of nanomaterials as additives. To This study investigates the effect of multilayer TisC2Tx MXenes at concentrations of 0.5, 1, 2, and 3 wt.-% on the thermal properties of nanofluids consisting of solar salt, thus aiming at enhancing the thermophysical performance for high-temperature thermal energy storage applications. This pioneering research explores how the concentration of MXene affects the specific heat capacity (Cp), melting temperature (Tm), and decomposition temperature (Td) of the nanofluids. Our results verified that adding MXenes to solar salt helps to enhance its thermal properties, particularly the decomposition temperature (Td) to 609.8 degrees C (compared to 586.2 degrees C for pure solar salt) and specific heat capacity (Cp), enabling better heat storage. These enhancements are attributed to structural and chemical effects induced by multilayer TisCaTx, as supported by experimental analyses (TGA, DSC, SEM, Raman spectroscopy, and XRD) and computational simulations. This demonstrates the potential of TisC2Tx for advancing high-temperature thermal energy storage systems in CSP plants.

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Disciplinas de Investigación



WOS
Physics, Applied
Energy & Fuels
Materials Science, Multidisciplinary
Scopus
Electronic, Optical And Magnetic Materials
Renewable Energy, Sustainability And The Environment
Surfaces, Coatings And Films
SciELO
Sin Disciplinas

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Publicaciones WoS (Ediciones: ISSHP, ISTP, AHCI, SSCI, SCI), Scopus, SciELO Chile.

Colaboración Institucional



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Autores - Afiliación



Ord. Autor Género Institución - País
1 Pineda, Fabiola - Universidad Mayor - Chile
2 Zambrano, Dario F. - Universidad de Chile - Chile
3 Lasanta, Maria Isabel - UNIV COMPLUTENSE MADRID - España
Universidad Complutense de Madrid - España
4 Guzman, Danny - Universidad de Atacama - Chile
5 Angel, Alejandro - Universidad Mayor - Chile
6 Palay, Francisco - Universidad Mayor - Chile
7 Rios, Paulina - Universidad Mayor - Chile
8 Gonzalez, Rafael I. - Universidad Mayor - Chile
Centro para el Desarrollo de la Nanociencia y la Nanotecnologia - Chile
9 RAMIREZ-GONZALEZ, MAZ ALBERTO Hombre Universidad de Chile - Chile
10 Rogan, Jose - Universidad de Chile - Chile
11 Valdivia, Juan Alejandro - Centro para el Desarrollo de la Nanociencia y la Nanotecnologia - Chile
Universidad de Chile - Chile
12 Perez, Francisco Javier - UNIV COMPLUTENSE MADRID - España
Universidad Complutense de Madrid - España
13 Rosenkranz, Andreas - Universidad de Chile - Chile
ANID – Millennium Science Initiative Program - Chile

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Financiamiento



Fuente
FONDECYT
FONDEQUIP
Fondo Nacional de Desarrollo Científico y Tecnológico
U.S. Department of Energy
Agencia Nacional de Investigación y Desarrollo
National Research and Development Agency
ANID-Chile
Millennium Science Initiative Program
ANID Post-Doctoral FONDECYT
Fondecyt de Exploracion
ANID projects.Chile within Solar Energy Research Center-SERC-Chile
ANID projects.Chile within Fondecyt
ANID-Chile in the Fondecyt Regular
ANID-Chile within Fondecyt

Muestra la fuente de financiamiento declarada en la publicación.

Agradecimientos



Agradecimiento
The authors would like to acknowledge the financial support provided by the National Research and Development Agency (Anid). F. Pineda gratefully acknowledges the support from projects of ANID projects.Chile within the projects Fondecyt Regular 1241151, Fondecyt de Exploracion 13240066, ANID/FONDAP/1523A0006 "Solar Energy Research Center-SERC-Chile" and Fondequip EQM170111. Dario F. Zambrano acknowledges the financial support funded by ANID post-doctoral FONDECYT (3220165) and FONDECYT project 1191779. Rafael I. Gonzalez acknowledges the support from projects ANID-Chile within the projects Fondecyt Regular 1241569 and Fondecyt de Exploracion 13240066. M. Ramirez acknowledges the financial support funded by ANID-Chile in the Fondecyt Regular 124063. J. Rogan ac-knowledges the financial support funded by ANID-Chile in the Fondecyt Regular 1240655. J. Valdivia acknowledges the financial support funded by ANID-Chile in the Fondecyt Regular 1240697. Finally, A. Rose-nkranz gratefully acknowledges the financial support of ANID-Chile within the projects Fondecyt Regular 1220331, Fondecyt de Exploracion 13240066 and Fondequip EQM190057 as well as and the Millennium Science Initiative Program (NCN2023_007).
The authors would like to acknowledge the financial support provided by the National Research and Development Agency (Anid). F. Pineda gratefully acknowledges the support from projects of ANID projects.Chile within the projects Fondecyt Regular 1241151, Fondecyt de Exploraci\u00F3n 13240066, ANID/FONDAP/1523A0006 \"Solar Energy Research Center - SERC-Chile\" and Fondequip EQM170111. Dario F. Zambrano acknowledges the financial support funded by ANID postdoctoral FONDECYT (3220165) and FONDECYT project 1191779. Rafael I. Gonz\u00E1lez acknowledges the support from projects ANID-Chile within the projects Fondecyt Regular 1241569 and Fondecyt de Exploraci\u00F3n 13240066. M. Ram\u00EDrez acknowledges the financial support funded by ANID-Chile in the Fondecyt Regular 124063. J. Rogan acknowledges the financial support funded by ANID-Chile in the Fondecyt Regular 1240655. J. Valdivia acknowledges the financial support funded by ANID-Chile in the Fondecyt Regular 1240697. Finally, A. Rosenkranz gratefully acknowledges the financial support of ANID-Chile within the projects Fondecyt Regular 1220331, Fondecyt de Exploraci\u00F3n 13240066 and Fondequip EQM190057 as well as and the Millennium Science Initiative Program (NCN2023_007).
The authors would like to acknowledge the financial support provided by the National Research and Development Agency (Anid). F. Pineda gratefully acknowledges the support from projects of ANID projects.Chile within the projects Fondecyt Regular 1241151, Fondecyt de Exploraci\u00F3n 13240066, ANID/FONDAP/1523A0006 \"Solar Energy Research Center - SERC-Chile\" and Fondequip EQM170111. Dario F. Zambrano acknowledges the financial support funded by ANID postdoctoral FONDECYT (3220165) and FONDECYT project 1191779. Rafael I. Gonz\u00E1lez acknowledges the support from projects ANID-Chile within the projects Fondecyt Regular 1241569 and Fondecyt de Exploraci\u00F3n 13240066. M. Ram\u00EDrez acknowledges the financial support funded by ANID-Chile in the Fondecyt Regular 124063. J. Rogan acknowledges the financial support funded by ANID-Chile in the Fondecyt Regular 1240655. J. Valdivia acknowledges the financial support funded by ANID-Chile in the Fondecyt Regular 1240697. Finally, A. Rosenkranz gratefully acknowledges the financial support of ANID-Chile within the projects Fondecyt Regular 1220331, Fondecyt de Exploraci\u00F3n 13240066 and Fondequip EQM190057 as well as and the Millennium Science Initiative Program (NCN2023_007).

Muestra la fuente de financiamiento declarada en la publicación.