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Synthesis and surface engineering of carbon-modified cobalt ferrite for advanced supercapacitor electrode materials
Indexado
WoS WOS:001360702700001
Scopus SCOPUS_ID:85209254810
DOI 10.1016/J.INOCHE.2024.113534
Año 2025
Tipo artículo de investigación

Citas Totales

Autores Afiliación Chile

Instituciones Chile

% Participación
Internacional

Autores
Afiliación Extranjera

Instituciones
Extranjeras


Abstract



The precise design and surface modification of electrode materials are crucial challenges for advancing the supercapacitor technology. In this study, we report a straightforward two-step process for the synthesis of a cobalt ferrite (CoFe2O4)/carbon hetero nanostructure. The CoFe2O4 nanoparticles were first synthesized using a simple chemical oxidation method, followed by carbon modification using glucose. The modified samples were calcined at 400 and 600 degrees C for 4 h in N2 atmosphere to optimize the structural and electrochemical properties. The increase in the grain size of carbon modified cobalt ferrite magnetic nanoparticles (MNPs) was observed from 22 to 28 nm with post annealing temperature. The presence of carbon was confirmed by the FTIR spectroscopy, FESEM and TEM analyses. The carbon decoration on the cobalt ferrite partially showed a core-shell like morphology. The saturation magnetization of bare cobalt ferrite was observed to be 76 emu/g and the same was decreased by the surface modification with carbon. A high specific capacitance of 323 F/g was observed for the carbon-modified cobalt ferrite MNPs annealed at 600 degrees C. The electrochemical impedance spectroscopy (EIS) analysis demonstrated that the charge-transfer resistance (Rct) decreased significantly in the carbon-modified CoFe2O4 MNPs, particularly for the sample annealed at 600 degrees C, with an Rctvalue of 17 Omega. The carbon layer effectively enhanced conductivity and reduced the electrode/electrolyte interface, led to the improved electrochemical performance, as reflected in the enhanced specific capacitance. An improved capacitance retention of 84 % was achieved in the case of carbon-modified cobalt ferrite MNPs based electrode even after 4000 cycles. The study suggested that the prepared carbon-modified cobalt ferrite MNPs stand in the limelight as a better candidate electrode material for the electrochemical applications.

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Disciplinas de Investigación



WOS
Chemistry, Inorganic & Nuclear
Scopus
Materials Chemistry
Inorganic Chemistry
Physical And Theoretical Chemistry
SciELO
Sin Disciplinas

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Publicaciones WoS (Ediciones: ISSHP, ISTP, AHCI, SSCI, SCI), Scopus, SciELO Chile.

Colaboración Institucional



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Autores - Afiliación



Ord. Autor Género Institución - País
1 Prabakaran, K. - KPR Inst Engn & Technol - India
KPR Institute of Engineering and Technology - India
2 Kavinkumar, T. - Karpagam Acad Higher Educ - India
Karpagam Academy of Higher Education - India
3 Shafi, P. Muhammed - Natl Inst Technol Calicut - India
National Institute of Technology Calicut - India
3 Muhammed Shafi, P. - National Institute of Technology Calicut - India
4 Shobin, L. R. - SRM Inst Sci & Technol SRMIST - India
SRM Institute of Science and Technology - India
5 MANGALARAJA, RAMALINGA VISWANATHAN - Universidad Adolfo Ibáñez - Chile
Universidad Arturo Prat - Chile
6 Bhaviripudi, Vijayabhaskara Rao - Universidad Tecnológica Metropolitana - Chile
7 Abarzua, Carolina Venegas - Universidad de Atacama - Chile
8 Thirumurugan, Arun Hombre Universidad de Atacama - Chile

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Financiamiento



Fuente
Agencia Nacional de Investigación y Desarrollo
Agencia Nacional de Investigacion y Desarrollo de Chile (ANID)

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Agradecimientos



Agradecimiento
This work was supported Agencia Nacional de Investigacion y Desarrollo de Chile (ANID) with a grant number SA 77210070.
This work was supported Agencia Nacional de Investigaci\u00F3n y Desarrollo de Chile (ANID) with a grant number SA 77210070 .

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