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Numerical and experimental investigation of a two-stage thermochemical water-splitting reactor based on a cerium oxide reduction-oxidation cycle
Indexado
WoS WOS:001360862900001
Scopus SCOPUS_ID:85209132215
DOI 10.1016/J.ENCONMAN.2024.119217
Año 2025
Tipo artículo de investigación

Citas Totales

Autores Afiliación Chile

Instituciones Chile

% Participación
Internacional

Autores
Afiliación Extranjera

Instituciones
Extranjeras


Abstract



Climate change has made clear the need to decarbonize the global energy matrix, and green hydrogen has emerged as a promising alternative fuel. In this framework, this work investigates the green hydrogen production by means of a two-stage thermochemical water-splitting reactor heated by both a parabolic dish receiver and a photovoltaic heater. A mathematical model is proposed to simulate reduction-oxidation process for the solar-powered reactor composed of a porous cerium oxide medium. Experimental and numerical thermal profiles show good agreement, with a high temperature in the reduction stage (>1100 K) and a lower temperature in the oxidation stage (860-715 K). Green hydrogen productions show maximum values close to 100 ppm and 2000 mu mol(H2O)/g(CeO2), for experimental and numerical tests, respectively. It is concluded that the photovoltaic heater is more relevant than the solar concentration heater, and that green hydrogen production could be improved by allowing longer residence times for the reduction-oxidation stages.

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Disciplinas de Investigación



WOS
Thermodynamics
Mechanics
Energy & Fuels
Physics, Nuclear
Scopus
Energy Engineering And Power Technology
Renewable Energy, Sustainability And The Environment
Fuel Technology
Nuclear Energy And Engineering
SciELO
Sin Disciplinas

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Publicaciones WoS (Ediciones: ISSHP, ISTP, AHCI, SSCI, SCI), Scopus, SciELO Chile.

Colaboración Institucional



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Autores - Afiliación



Ord. Autor Género Institución - País
1 ROJAS-GONZALEZ, PAULA JAVIERA Mujer Universidad Técnica Federico Santa María - Chile
2 Alegria, Nicolas - Universidad Técnica Federico Santa María - Chile
3 TOLEDO-TORRES, MARIO GONZALO Hombre Universidad Técnica Federico Santa María - Chile

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Financiamiento



Fuente
Fondo de Fomento al Desarrollo Científico y Tecnológico
Agencia Nacional de Investigación y Desarrollo
ANID-Chile
National Agency for Research and Development (ANID-Chile)
Agenția Națională pentru Cercetare și Dezvoltare
Graduate and Programs Department of the Universidad Tecnica Federico Santa Maria, Chile
Graduate and Programs Department of the Universidad Técnica Federico Santa María

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Agradecimientos



Agradecimiento
The authors would like to express their gratitude to the Graduate and Programs Department of the Universidad Tecnica Federico Santa Maria, Chile, for their financial support through the Scholarship and Financial Aid, and to the National Agency for Research and Development (ANID-Chile) (Project FONDAP 1523A006/SERC-Chile and FONDEF VIU 23P0116) .
The authors would like to express their gratitude to the Graduate and Programs Department of the Universidad T\u00E9cnica Federico Santa Mar\u00EDa, Chile, for their financial support through the Scholarship and Financial Aid, and to the National Agency for Research and Development (ANID-Chile) (Project FONDAP 1523A006/SERC-Chile and FONDEF VIU 23P0116).
The authors would like to express their gratitude to the Graduate and Programs Department of the Universidad T\u00E9cnica Federico Santa Mar\u00EDa, Chile, for their financial support through the Scholarship and Financial Aid, and to the National Agency for Research and Development (ANID-Chile) (Project FONDAP 1523A006/SERC-Chile and FONDEF VIU 23P0116).

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