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The correlation between surface scaling behavior and optical properties of NiO thin films nanostructures: An investigation based on fractal concepts
Indexado
WoS WOS:001328253900001
Scopus SCOPUS_ID:85201093715
DOI 10.1016/J.CERAMINT.2024.08.011
Año 2024
Tipo artículo de investigación

Citas Totales

Autores Afiliación Chile

Instituciones Chile

% Participación
Internacional

Autores
Afiliación Extranjera

Instituciones
Extranjeras


Abstract



Here, we report room temperature deposition of nickel oxide (NiO) thin films on silicon and glass substrates by direct current (dc) magnetron sputtering using a metallic nickel target. The effect of sputtering power (20 W, 25 W, and 30 W) on the thin films, their surface scaling, fractal dimension, and optical properties are extensively investigated. Autocorrelation and height–height correlation functions were applied to AFM images to extract deep insights about the thin films' surfaces. Fractal dimension (Df) was extracted through the power spectral density (PSD) function. Various scaling exponents, including α, β, and 1/z, of the NiO film's surface were independently observed. The local roughness exponent, α, was approximately 0.81 for films deposited with 20 W sputtering power and decreased to 0.71 with higher sputtering power. The interface width (σ) scales with sputtering power (Sp) as ∼ Spβ, with a growth exponent (β) value of 1.17. The lateral correlation length (ξ) follows as ∼ Sp1/z with a 1/z value of 0.703. Additionally, optical parameters were recorded through UV–Vis. optical spectroscopy, and an attempt was made to correlate them with fractal parameters (Df & α). Optical absorption (reflection) increased (decreased) with increasing Df values. The minimum (maximum) reflection (absorption) was observed on the roughest surface (Df = 2.29). The calculated band gap decreased with increasing fractal dimension. This investigation suggests that sputtered surfaces with minimal reflectivity, band gap, and enhanced light-absorbing capacity could potentially be used as active solar layers for advanced optoelectronic devices.

Revista



Revista ISSN
Ceramics International 0272-8842

Métricas Externas



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Disciplinas de Investigación



WOS
Materials Science, Ceramics
Scopus
Materials Chemistry
Electronic, Optical And Magnetic Materials
Process Chemistry And Technology
Ceramics And Composites
Surfaces, Coatings And Films
SciELO
Sin Disciplinas

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Publicaciones WoS (Ediciones: ISSHP, ISTP, AHCI, SSCI, SCI), Scopus, SciELO Chile.

Colaboración Institucional



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Autores - Afiliación



Ord. Autor Género Institución - País
1 Kumar, Chandra - Universidad Mayor - Chile
2 Shrivastav, Monika - Malaviya National Institute of Technology Jaipur - India
Malaviya Natl Inst Technol - India
3 Escrig, Juan - Centro para el Desarrollo de la Nanociencia y la Nanotecnologia - Chile
Universidad de Santiago de Chile - Chile
4 PALMA-SOLORZA, JUAN LUIS Hombre Universidad Central de Chile - Chile
5 Yadav, R. P. - Govt. P.G. College - India
Mahamaya Government Degree College Manjhanpur - India
Govt PG Coll - India
Mahamaya Govt Degree Coll Manjhanpur - India
6 Silva, Héctor - Universidad de Antofagasta - Chile
7 Zarate, Antonio - Universidad Católica del Norte - Chile

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Financiamiento



Fuente
FONDECYT
FONDEQUIP
Fondo Nacional de Desarrollo Científico y Tecnológico
Universidad Católica del Norte
Financiamiento Basal para Centros Científicos y Tecnológicos de Excelencia
CEDENNA through Financiamiento Basal para Centros Cientificos y Tecnologicos de Excelencia
Centro para el Desarrollo de la Nanociencia y la Nanotecnologia
POSTDOC_ANID

Muestra la fuente de financiamiento declarada en la publicación.

Agradecimientos



Agradecimiento
This work was supported by CEDENNA through Financiamiento Basal para Centros Cient\u00EDficos y Tecnol\u00F3gicos de Excelencia (Grant AFB220001). We also acknowledge support from FONDECYT (Grant 1240829) and POSTDOC_ANID (Grant 3240551). The authors acknowledge FONDECYT 1130984, FONDEQUIP EQM160120. Also, the authors acknowledge the Maine, UCN for UV-Vis. optical spectroscopy
This work was supported by CEDENNA through Financiamiento Basal para Centros Cient\u00EDficos y Tecnol\u00F3gicos de Excelencia (Grant AFB220001). We also acknowledge support from FONDECYT (Grant 1240829) and POSTDOC_ANID (Grant 3240551). The authors acknowledge FONDECYT 1130984, FONDEQUIP EQM160120. Also, the authors acknowledge the Maine, UCN for UV-Vis. optical spectroscopy
This work was supported by CEDENNA through Financiamiento Basal para Centros Cientificos y Tecnologicos de Excelencia (Grant AFB220001) . We also acknowledge support from FONDECYT (Grant 1240829) and POSTDOC_ANID (Grant 3240551) . The fondequip (EQM 210088) was supported for AFM testing. The authors acknowledge FONDECYT 1130984, FONDEQUIP EQM160120. Also, the authors acknowledge the Maini, UCN for UV-Vis. optical spectroscopy.

Muestra la fuente de financiamiento declarada en la publicación.