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Effects of interfacial oxygen diffusion on the magnetic properties and thermal stability of Pd/CoFeB/Pd/Ta heterostructure
Indexado
WoS WOS:001315819300001
Scopus SCOPUS_ID:85203629877
DOI 10.1016/J.JALLCOM.2024.176382
Año 2024
Tipo artículo de investigación

Citas Totales

Autores Afiliación Chile

Instituciones Chile

% Participación
Internacional

Autores
Afiliación Extranjera

Instituciones
Extranjeras


Abstract



We investigated the effects of annealing temperatures (TA) on a Pd (5 nm)/CoFeB (10 nm)/Pd (3 nm)/Ta (10 nm) multilayer structure. The as-deposited sample showed an amorphous state with in-plane uniaxial magnetic anisotropy (UMA), resulting in low coercivity and moderate Gilbert damping constant (α) values. Increasing TA led to crystallization, forming bcc-CoFe (110) crystals, which increased in-plane coercivity and introduced isotropic magnetic anisotropy, slightly reducing the α. The two-fold UMA persists up to 600 °C, and the thermal stability of the in-plane magnetic anisotropy remains intact even TA = 700 °C. The TA significantly influenced the magnetic properties such as in-plane saturation magnetization (Ms//), in-plane and out-of-plane coercivities (Hc// and Hc⊥), and in-plane effective magnetic anisotropy energy density (Keff). Above 600 °C, Keff decreased, indicating a transition towards uniaxial perpendicular magnetic anisotropy. Interfacial oxidation and diffusion from the Ta capping layer to the Pd/CoFeB/Pd interfaces were observed, influencing chemical bonding states. Annealing at 700 °C, reduced oxygen within TaOx through a redox reaction involving Ta crystallization, forming TaB, PdO, and BOx states. Ferromagnetic resonance spectra analysis indicated variations in resonance field (Hr) due to local chemical environments. The α reduction, reaching a minimum at 300 °C annealing, was attributed to reduced structural disorder from inhomogeneities. Tailoring magnetic anisotropy and spin dynamic properties in Pd/CoFeB/Pd/Ta structures through TA-controlled oxygen diffusion/oxidation highlights their potential for SOT, DMI, and magnetic skyrmion-based spintronic devices.

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Disciplinas de Investigación



WOS
Chemistry, Physical
Metallurgy & Metallurgical Engineering
Materials Science, Multidisciplinary
Scopus
Materials Chemistry
Mechanics Of Materials
Mechanical Engineering
Metals And Alloys
SciELO
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Publicaciones WoS (Ediciones: ISSHP, ISTP, AHCI, SSCI, SCI), Scopus, SciELO Chile.

Colaboración Institucional



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Autores - Afiliación



Ord. Autor Género Institución - País
1 Lakshmanan, Saravanan - Universidad Técnica Federico Santa María - Chile
2 Romanque-Albornoz, Cristian Hombre Universidad Técnica Federico Santa María - Chile
3 Mery, Mario Hombre Universidad Técnica Federico Santa María - Chile
4 Muthuvel, Manivel Raja - DRDO Defence Metallurgical Research Laboratory - India
Def Met Res Lab - India
5 Gupta, Nanhe Kumar - Indian Institute of Technology Delhi - India
Indian Inst Technol Delhi - India
6 Garcia, Carlos - Universidad Técnica Federico Santa María - Chile

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Financiamiento



Fuente
Fondo Nacional de Desarrollo Científico y Tecnológico
Horizon 2020
Horizon 2020 Framework Programme
ANID FONDEQUIP

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Agradecimientos



Agradecimiento
L. Saravanan acknowledges to FONDECYT Postdoctorado 2022 ANID, 3220373. C. Garcia acknowledges the financial support received by ANID FONDECYT/Regular 1201102, ANID FONDECYT/Regular 1241918, ANID FONDEQUIP EQM140161, and ANID FONDEQUIP EQM 150094. This work was also supported by the European Union\u2019s Horizon 2020 research and innovation program under the Marie Sklodowska-Curie Grant Agreement No. 734801 (MAGNAMED) and No. 101007825 (ULTIMATE-I).
L. Saravanan acknowledges to FONDECYT Postdoctorado 2022 ANID, 3220373. C. Garcia acknowledges the financial support received by ANID FONDECYT/Regular 1201102, ANID FONDECYT/Regular 1241918, ANID FONDEQUIP EQM140161, and ANID FONDEQUIP EQM 150094. This work was also supported by the European Union\u2019s Horizon 2020 research and innovation program under the Marie Sklodowska-Curie Grant Agreement No. 734801 (MAGNAMED) and No. 101007825 (ULTIMATE-I).

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