Regolith-hosted rare earth element deposits (RH-REE) have been recently found in Chile, nonetheless their ore formation controls, which include temperate to arid climate, intrusive rocks with weatherable REE minerals, and gentle slopes or pediplains, among others, differ from the most common deposits in Asia. This work addresses mineralization and exploration methods for RH-REE deposits across the Chilean Coastal Range. The studied prospect is associated with late Carboniferous I-type tonalitic intrusions. Mineralogical analysis (TIMA-X) indicates that allanite and monazite are the main REE-bearing minerals in the host rock. The regolith in the study area is up to 60 m deep and contains an exchangeable-REE concentration up to 2000 ppm, as determined by portable X-ray fluorescence (pXRF) and ICP-MS. We were able to recognize that REE-adsorption takes place both in preserved and partially eroded regoliths. Progressive weathering of these regoliths causes the pedolith/saprolith limit to be dynamic and accumulate REE due to the breakdown of allanite and monazite. Our data shows that the search for pediplains on suitable lithologies, mapping of regolith profiles, and their analysis via pXRF by quantifying yttrium, appears to be a suitable strategy for early exploration of RH-REE deposits in the Chilean Coastal Range.