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Optimizing bone and biomass co-torrefaction parameters: High-performance arsenic removal from wastewater via co-torrefied bone char
Indexado
WoS WOS:001239402600001
Scopus SCOPUS_ID:85192137990
DOI 10.1016/J.ENVRES.2024.118990
Año 2024
Tipo artículo de investigación

Citas Totales

Autores Afiliación Chile

Instituciones Chile

% Participación
Internacional

Autores
Afiliación Extranjera

Instituciones
Extranjeras


Abstract



This study aimed to investigate bone char's physicochemical transformations through co-torrefaction and co-pyrolysis processes with biomass. Additionally, it aimed to analyze the carbon sequestration process during co-torrefaction of bone and biomass and optimize the process parameters of co-torrefaction. Finally, the study sought to evaluate the arsenic sorption capacity of both torrefied and co-torrefied bone char. Bone and biomass co-torrefaction was conducted at 175 degrees C-300 degrees C. An orthogonal array of Taguchi techniques and artificial neural networks (ANN) were employed to investigate the influence of various torrefaction parameters on carbon dioxide sequestration within torrefied bone char. A co-torrefied bone char, torrefied at a reaction temperature of 300 degrees C, a heating rate of 15 degrees C<middle dot>min(-1), and mixed with 5 g m of biomass (wood dust), was selected for the arsenic (III) sorption experiment due to its elevated carbonate content. The results revealed a higher carbonate fraction (21%) in co-torrefied bone char at 300 degrees C compared to co-pyrolyzed bone char (500-700 degrees C). Taguchi and artificial neural network (ANN) analyses indicated that the relative impact of process factors on carbonate substitution in bone char followed the order of co-torrefaction temperature (38.8%) > heating rate (31.06%) > addition of wood biomass (30.1%). Co-torrefied bone chars at 300 degrees C exhibited a sorption capacity of approximately 3 mg g(-1), surpassing values observed for pyrolyzed bone chars at 900 degrees C in the literature. The findings suggest that co-torrefied bone char could serve effectively as a sorbent in filters for wastewater treatment and potentially fulfill roles such as a remediation agent, pH stabilizer, or valuable source of biofertilizer in agricultural applications.

Revista



Revista ISSN
Environmental Research 0013-9351

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Disciplinas de Investigación



WOS
Public, Environmental & Occupational Health
Environmental Sciences
Scopus
Sin Disciplinas
SciELO
Sin Disciplinas

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Publicaciones WoS (Ediciones: ISSHP, ISTP, AHCI, SSCI, SCI), Scopus, SciELO Chile.

Colaboración Institucional



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Autores - Afiliación



Ord. Autor Género Institución - País
1 Chen, Wei Hsin - Natl Cheng Kung Univ - Taiwán
Tunghai Univ - Taiwán
Natl Chin Yi Univ Technol - Taiwán
National Cheng Kung University - Taiwán
Tunghai University - Taiwán
National Chin-Yi University of Technology - Taiwán
2 Biswas, Partha Pratim - Tunghai Univ - Taiwán
Tunghai University - Taiwán
3 Kwon, Eilhann E. - Hanyang Univ - Corea del Sur
Hanyang University - Corea del Sur
4 Lin, Kun-Yi Andrew - Natl Chung Hsing Univ - Taiwán
Natl Tsing Hua Univ - Taiwán
National Cheng Kung University - Taiwán
National Tsing Hua University - Taiwán
National Chung Hsing University - Taiwán
5 Rajendran, Saravanan - Universidad de Tarapacá - Chile
6 Chang, Jo Shu - Tunghai Univ - Taiwán
Natl Cheng Kung Univ - Taiwán
Tunghai University - Taiwán
National Cheng Kung University - Taiwán

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Financiamiento



Fuente
National Science and Technology Council
National Science and Technology Council, Taiwan, R.O.C

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Agradecimientos



Agradecimiento
The authors gratefully acknowledge the financial support from the National Science and Technology Council, Taiwan, R.O.C, under the contracts NSTC 113-2222-E-029-001-, NSTC 112-2218-E-006-025-, and NSTC 112-2218-E-002-052- for this study.
The authors gratefully acknowledge the financial support from the National Science and Technology Council, Taiwan, R.O.C, under the contracts NSTC 113-2222-E-029-001-, NSTC 112-2218-E-006-025-, and NSTC 112-2218-E-002-052- for this study.

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