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| DOI | 10.1016/J.ENVRES.2024.118990 | ||||
| Año | 2024 | ||||
| Tipo | artículo de investigación |
Citas Totales
Autores Afiliación Chile
Instituciones Chile
% Participación
Internacional
Autores
Afiliación Extranjera
Instituciones
Extranjeras
This study aimed to investigate bone char's physicochemical transformations through co-torrefaction and co-pyrolysis processes with biomass. Additionally, it aimed to analyze the carbon sequestration process during co-torrefaction of bone and biomass and optimize the process parameters of co-torrefaction. Finally, the study sought to evaluate the arsenic sorption capacity of both torrefied and co-torrefied bone char. Bone and biomass co-torrefaction was conducted at 175 degrees C-300 degrees C. An orthogonal array of Taguchi techniques and artificial neural networks (ANN) were employed to investigate the influence of various torrefaction parameters on carbon dioxide sequestration within torrefied bone char. A co-torrefied bone char, torrefied at a reaction temperature of 300 degrees C, a heating rate of 15 degrees C<middle dot>min(-1), and mixed with 5 g m of biomass (wood dust), was selected for the arsenic (III) sorption experiment due to its elevated carbonate content. The results revealed a higher carbonate fraction (21%) in co-torrefied bone char at 300 degrees C compared to co-pyrolyzed bone char (500-700 degrees C). Taguchi and artificial neural network (ANN) analyses indicated that the relative impact of process factors on carbonate substitution in bone char followed the order of co-torrefaction temperature (38.8%) > heating rate (31.06%) > addition of wood biomass (30.1%). Co-torrefied bone chars at 300 degrees C exhibited a sorption capacity of approximately 3 mg g(-1), surpassing values observed for pyrolyzed bone chars at 900 degrees C in the literature. The findings suggest that co-torrefied bone char could serve effectively as a sorbent in filters for wastewater treatment and potentially fulfill roles such as a remediation agent, pH stabilizer, or valuable source of biofertilizer in agricultural applications.
| Ord. | Autor | Género | Institución - País |
|---|---|---|---|
| 1 | Chen, Wei Hsin | - |
Natl Cheng Kung Univ - Taiwán
Tunghai Univ - Taiwán Natl Chin Yi Univ Technol - Taiwán National Cheng Kung University - Taiwán Tunghai University - Taiwán National Chin-Yi University of Technology - Taiwán |
| 2 | Biswas, Partha Pratim | - |
Tunghai Univ - Taiwán
Tunghai University - Taiwán |
| 3 | Kwon, Eilhann E. | - |
Hanyang Univ - Corea del Sur
Hanyang University - Corea del Sur |
| 4 | Lin, Kun-Yi Andrew | - |
Natl Chung Hsing Univ - Taiwán
Natl Tsing Hua Univ - Taiwán National Cheng Kung University - Taiwán National Tsing Hua University - Taiwán National Chung Hsing University - Taiwán |
| 5 | Rajendran, Saravanan | - |
Universidad de Tarapacá - Chile
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| 6 | Chang, Jo Shu | - |
Tunghai Univ - Taiwán
Natl Cheng Kung Univ - Taiwán Tunghai University - Taiwán National Cheng Kung University - Taiwán |
| Fuente |
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| National Science and Technology Council |
| National Science and Technology Council, Taiwan, R.O.C |
| Agradecimiento |
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| The authors gratefully acknowledge the financial support from the National Science and Technology Council, Taiwan, R.O.C, under the contracts NSTC 113-2222-E-029-001-, NSTC 112-2218-E-006-025-, and NSTC 112-2218-E-002-052- for this study. |
| The authors gratefully acknowledge the financial support from the National Science and Technology Council, Taiwan, R.O.C, under the contracts NSTC 113-2222-E-029-001-, NSTC 112-2218-E-006-025-, and NSTC 112-2218-E-002-052- for this study. |