This study reveals a groundbreaking advancement in utilizing carbon dioxide (CO2) for syngas production through methane (CH4) dry reforming using Fibrous Silica Titania (FST) as a support, loaded with different (1%, 3%, and 5%) nickel dosages. FST is distinguished by its fibrous structure, maintains a stable temperature, facilitates the confinement and dispersion of active metal, and is exceptionally effective at preventing carbon deposition. For a thorough examination of the new catalysts, characterization methods including XRD, FESEM, EDX mapping, N2 physisorption, FTIR-KBr, H2-TPR, and CO2-TPD were employed. Importantly, TEM lattice fringes verified the existence of XRD peaks and planes of Ni (111), Ni (200), and TiO2 (101). Aspects such as O-H stretching, Si-O-Si asymmetry, vibrations caused by external Si-OH groups, and Si-O-Si bending were identified using FTIR-KBr analysis. The study ingeniously identified the superior (3Ni/FST) catalyst, which exhibited moderate basicity sites on the CO2-TPD at approximately 350 degrees C. The catalyst converted nearly 100% CH4 at 750 degrees C with minimal coke production and 80% CO2 at 850 degrees C. Surprisingly, the 3Ni/FST catalyst demonstrated remarkable stability during a 72 h TOS stability test at 650 degrees C, effectively preventing coke-forming side reactions such as CO disproportionation, CO hydrogenation, CO2 and CH4 cracking with syngas ratio around unity and little coke production. The FST support exhibited exceptional attributes for low temperature carbon neutral CH4 reforming.