Cosmological scenarios with a non-standard equation of state can involve ultrastiff fluids, understood as primordial fluids for which p/rho > 1. Their energy densities can dominate the Universe energy budget at early times, in the otherwise radiation dominated epoch. During that period the Universe undergoes a faster expansion, that has implications for any decoupling process that takes place in that era. Quintessence models or Ekpyrotic cosmologies are good examples of such scenarios. Assuming the ultrastiff state to be thermally decoupled at very early times, if ever coupled, its observational imprints are left solely in the Universe expansion rate and in the radiation energy density. We consider a complete set of ultrastiff fluids and study their signatures in the neutrino decoupling and BBN eras. Measurements of N-eff alone place mild constraints on these scenarios, with forthcoming measurements from the Simons Observatory in the Chilean Atacama desert being able to test regions where still sizable effects are observable. However, when BBN data is taken into account, those regions are proven to be barely reconcilable with primordial helium-4 and deuterium abundances measurements. Our findings show that measurements of the primordial helium-4 abundance imply the tightest constraints, with measurements of primordial deuterium being - to a certain extent - competitive as well. We point out that a similar to 60% improvement on the statistical uncertainty of the primordial helium-4 abundance measurement, will test these scenarios in the region where they can produce sizable effects. Beyond that precision the regions that are accessible degenerate with standard expectations. In that case, although potentially present, neither neutrino decoupling nor BBN observables will be sensitive probes.