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SrCo0.50Fe0.40Ir0.10O3−δ Decorated with Pd and La0.8Sr0.2Ga0.83Mg0.17O3−δ: A Cleaner Electrode for Intermediate-Temperature Solid Oxide Fuel Cells with Reduced Cobalt Content
Indexado
WoS WOS:001161581300001
Scopus SCOPUS_ID:85183022249
DOI 10.1021/ACSAEM.3C02361
Año 2024
Tipo artículo de investigación

Citas Totales

Autores Afiliación Chile

Instituciones Chile

% Participación
Internacional

Autores
Afiliación Extranjera

Instituciones
Extranjeras


Abstract



Recent studies related to cathode materials for solid oxide fuel cells (SOFCs) have showcased the feasibility of stabilizing cubic or tetragonal perovskite phases in the SrCoO3-delta system at room temperature. This achievement has been facilitated by partially substituting Co atoms with small amounts of highly charged cations such as Ir4+ in SrCo0.90Ir0.10O3-delta. This specific material exhibits exceptional performance as a cathode for SOFCs operating at intermediate temperatures (800-850 degrees C). However, it contains a high amount of cobalt, which is both costly and toxic. In this study, our focus has been on further improving this material by reducing its cobalt content, resulting in a cleaner and more cost-effective cathode for SOFCs. The resulting SrCo0.50Fe0.40Ir0.10O3-delta perovskite, synthesized by the citrate method, introduces a 40% composition of Fe in the sites of Co and Ir, effectively decreasing the amount of Co in the material. The crystal structure of this perovskite oxide has been analyzed using X-ray diffraction (XRD) and neutron powder diffraction (NPD), allowing us to establish correlations with its mechanical and electrical properties. In the single-cell test, this material gave reasonable performances as a cathode at intermediate temperatures (800-850 degrees C), with La0.8Sr0.2Ga0.83Mg0.17O3-delta (LSGM) as the electrolyte. An analysis of the chemical compatibility between the cathode and the electrolyte, LSGM, demonstrated no interaction at elevated temperatures. Thermal expansion coefficient (TEC) measurements exhibited consistent linear expansion across the entire temperature range. Lastly, the perovskite displayed commendable electrical conductivity along with a promising power density measurement of 384 mW/cm(2) at 850 degrees C. These findings collectively suggest the potential of this material as a viable cleaner cathode option for intermediate-temperature SOFCs. Moreover, the cathode was further optimized and the performance of the cell improved, by either infiltrating SrCo0.50Fe0.40Ir0.10O3-delta with a Pd(NO3)(2) solution or mixing it with 30% of LSGM electrolyte, resulting in higher power densities (568 and 675 mW/cm(2), respectively) in test cells fed with pure H-2 as a fuel.

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Disciplinas de Investigación



WOS
Chemistry, Physical
Energy & Fuels
Materials Science, Multidisciplinary
Scopus
Chemical Engineering (Miscellaneous)
Energy Engineering And Power Technology
Electrochemistry
Materials Chemistry
Electrical And Electronic Engineering
SciELO
Sin Disciplinas

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Publicaciones WoS (Ediciones: ISSHP, ISTP, AHCI, SSCI, SCI), Scopus, SciELO Chile.

Colaboración Institucional



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Autores - Afiliación



Ord. Autor Género Institución - País
1 Chivite-Lacaba, Monica Mujer UNIV COMPLUTENSE MADRID - España
CSIC - España
Universidad Complutense de Madrid - España
CSIC - Instituto de Ciencia de Materiales de Madrid (ICMM) - España
2 Prado-Gonjal, Jesus Hombre CSIC - España
CSIC - Instituto de Ciencia de Materiales de Madrid (ICMM) - España
3 TRONCOSO-AGUILERA, LORETO DEL PILAR Mujer Universidad Austral de Chile - Chile
4 Antonio Alonso, Jose - UNIV COMPLUTENSE MADRID - España
Universidad Complutense de Madrid - España
4 ALONSO-ALONSO, JOSE ANTONIO Hombre Universidad Complutense de Madrid - España
5 Cascos, V. Mujer UNIV COMPLUTENSE MADRID - España
CSIC - España
Universidad Complutense de Madrid - España
CSIC - Instituto de Ciencia de Materiales de Madrid (ICMM) - España

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Financiamiento



Fuente
FONDECYT
Fondo Nacional de Desarrollo Científico y Tecnológico
Ministerio de Ciencia e Innovación
Comunidad de Madrid
Institut Laue-Langevin
MCIN
Millennium Institute of Green Ammonia as Energy Vector MIGA
Community of Madrid-Universidad Complutense de Madrid

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Agradecimientos



Agradecimiento
J.A.A. is thankful for the financial support of the MCIN for funding the project number: PID2021-122477OB-I00. We acknowledge the Institut Laue-Langevin (ILL) for making all facilities available. V.C. and J.P.G. thank the MCIN (MCIN/AEI/10.13039/501100011033) for granting the project PID2020-112848RB-C21. V.C. and J.P.G. appreciate the support of Community of Madrid-Universidad Complutense de Madrid for the concession of the project PR27/21-002 and for granting the "Atraccion de Talento program" fellowship, 2019-T2/IND-13483. L.T. is thankful for the project Fondecyt Regular 1220630 and the Millennium Institute of Green Ammonia as Energy Vector MIGA, ANID/Millennium Science Initiative Program/ICN2021_023.
J.A.A. is thankful for the financial support of the MCIN for funding the project number: PID2021-122477OB-I00. We acknowledge the Institut Laue-Langevin (ILL) for making all facilities available. V.C. and J.P.G. thank the MCIN (MCIN/AEI/10.13039/501100011033) for granting the project PID2020-112848RB-C21. V.C. and J.P.G. appreciate the support of Community of Madrid-Universidad Complutense de Madrid for the concession of the project PR27/21-002 and for granting the “Atracción de Talento program” fellowship, 2019-T2/IND-13483. L.T. is thankful for the project Fondecyt Regular 1220630 and the Millennium Institute of Green Ammonia as Energy Vector MIGA, ANID/Millennium Science Initiative Program/ICN2021_023.

Muestra la fuente de financiamiento declarada en la publicación.