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A Reversible Fluorescent Chemosensor for the Selective Detection of Cu2+ and CN- ions by Displacement Approach
Indexado
WoS WOS:001063911900002
Scopus SCOPUS_ID:85168916176
DOI 10.1007/S10895-023-03381-2
Año 2024
Tipo artículo de investigación

Citas Totales

Autores Afiliación Chile

Instituciones Chile

% Participación
Internacional

Autores
Afiliación Extranjera

Instituciones
Extranjeras


Abstract



A novel fluorescence chemosensor BDP (2-(1-(benzothiazol-2-yl)-5-(4-(diphenylamino)phenyl)-4,5-dihydro-1H-pyrazol-3-yl)phenol) has been synthesized and its sensing behavior has been screened towards various cations by absorption, emission and mass spectroscopic techniques. The probe BDP detects Cu2+ ions preferentially over other metal ions, and the resulting BDP-Cu2+ ensemble acts as a secondary sensor for cyanide anion detection over other anions. The fluorescence intensity of the probe BDP is quenched when it comes into contact with Cu2+ ions, but it is increased reversibly when it comes into contact with cyanide anion, according to spectroscopic measurements. Along with this, optical studies indicate that the sensor BDP has capability to sense Cu2+ and CN- ions selectively over other examined competitive ions with the LOD of 2.57x10(-8) M and 2.98x10(-8) M respectively. The detection limit of Cu2+ ions is lower than the WHO recommended Cu2+ ions concentration (31.5 mu M) in drinking water. On the basis of "on-off-on" fluorescence change of the probe BDP upon interaction with Cu2+ and CN- ions, a possible mechanism for this selective sensing behavior was presented and IMPLICATION logic gate was successfully designed. Furthermore, cell imaging investigations were used to investigate the probe BDP's biological applicability.

Revista



Revista ISSN
Journal Of Fluorescence 1053-0509

Métricas Externas



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Disciplinas de Investigación



WOS
Chemistry, Physical
Chemistry, Analytical
Biochemical Research Methods
Scopus
Sin Disciplinas
SciELO
Sin Disciplinas

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Publicaciones WoS (Ediciones: ISSHP, ISTP, AHCI, SSCI, SCI), Scopus, SciELO Chile.

Colaboración Institucional



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Autores - Afiliación



Ord. Autor Género Institución - País
1 Viswanathamurthi, Periasamy - Periyar Univ - India
Periyar University - India
2 Dhivya, Rajasekaran - Periyar Univ - India
Periyar University - India
3 Kavitha, Venkatachalam - Periyar Univ - India
Periyar University - India
4 Haribabu, Jebiti - Universidad de Atacama - Chile
5 Echeverria, Cesar A. Hombre Universidad de Atacama - Chile

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Financiamiento



Fuente
University Grants Commission
Council of Scientific and Industrial Research, India
Council of Scientific and Industrial Research (CSIR), Delhi, India
University Grants Commission (UGC), India [SAP]

Muestra la fuente de financiamiento declarada en la publicación.

Agradecimientos



Agradecimiento
The authors express their sincere thanks to the Council of Scientific and Industrial Research (CSIR), Delhi, India [Grant No. 01 (2907)/17/EMR-II] and the University Grants Commission (UGC), India [SAP grant No. 540/20/DRS-I/2016(SAP-I)] for financial assistance.
The work is supported by Council of Scientific and Industrial Research (CSIR), Delhi, India [Grant No. 01 (2907)/17/EMR-II] and partially supported by the University Grants Commission (UGC), India [SAP grant No. 540/20/DRS-I/2016(SAP-I)].

Muestra la fuente de financiamiento declarada en la publicación.