Muestra métricas de impacto externas asociadas a la publicación. Para mayor detalle:
| Indexado |
|
||||
| DOI | 10.1007/S10895-023-03381-2 | ||||
| Año | 2024 | ||||
| Tipo | artículo de investigación |
Citas Totales
Autores Afiliación Chile
Instituciones Chile
% Participación
Internacional
Autores
Afiliación Extranjera
Instituciones
Extranjeras
A novel fluorescence chemosensor BDP (2-(1-(benzothiazol-2-yl)-5-(4-(diphenylamino)phenyl)-4,5-dihydro-1H-pyrazol-3-yl)phenol) has been synthesized and its sensing behavior has been screened towards various cations by absorption, emission and mass spectroscopic techniques. The probe BDP detects Cu2+ ions preferentially over other metal ions, and the resulting BDP-Cu2+ ensemble acts as a secondary sensor for cyanide anion detection over other anions. The fluorescence intensity of the probe BDP is quenched when it comes into contact with Cu2+ ions, but it is increased reversibly when it comes into contact with cyanide anion, according to spectroscopic measurements. Along with this, optical studies indicate that the sensor BDP has capability to sense Cu2+ and CN- ions selectively over other examined competitive ions with the LOD of 2.57x10(-8) M and 2.98x10(-8) M respectively. The detection limit of Cu2+ ions is lower than the WHO recommended Cu2+ ions concentration (31.5 mu M) in drinking water. On the basis of "on-off-on" fluorescence change of the probe BDP upon interaction with Cu2+ and CN- ions, a possible mechanism for this selective sensing behavior was presented and IMPLICATION logic gate was successfully designed. Furthermore, cell imaging investigations were used to investigate the probe BDP's biological applicability.
| Ord. | Autor | Género | Institución - País |
|---|---|---|---|
| 1 | Viswanathamurthi, Periasamy | - |
Periyar Univ - India
Periyar University - India |
| 2 | Dhivya, Rajasekaran | - |
Periyar Univ - India
Periyar University - India |
| 3 | Kavitha, Venkatachalam | - |
Periyar Univ - India
Periyar University - India |
| 4 | Haribabu, Jebiti | - |
Universidad de Atacama - Chile
|
| 5 | Echeverria, Cesar A. | Hombre |
Universidad de Atacama - Chile
|
| Fuente |
|---|
| University Grants Commission |
| Council of Scientific and Industrial Research, India |
| Council of Scientific and Industrial Research (CSIR), Delhi, India |
| University Grants Commission (UGC), India [SAP] |
| Agradecimiento |
|---|
| The authors express their sincere thanks to the Council of Scientific and Industrial Research (CSIR), Delhi, India [Grant No. 01 (2907)/17/EMR-II] and the University Grants Commission (UGC), India [SAP grant No. 540/20/DRS-I/2016(SAP-I)] for financial assistance. |
| The work is supported by Council of Scientific and Industrial Research (CSIR), Delhi, India [Grant No. 01 (2907)/17/EMR-II] and partially supported by the University Grants Commission (UGC), India [SAP grant No. 540/20/DRS-I/2016(SAP-I)]. |