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Thermoelectric Properties of Cotton Fabrics Dip-Coated in Pyrolytically Stripped Pyrograf<SUP>®</SUP> III Carbon Nanofiber Based Aqueous Inks
Indexado
WoS WOS:001017196500001
Scopus SCOPUS_ID:85163719099
DOI 10.3390/MA16124335
Año 2023
Tipo artículo de investigación

Citas Totales

Autores Afiliación Chile

Instituciones Chile

% Participación
Internacional

Autores
Afiliación Extranjera

Instituciones
Extranjeras


Abstract



The transport properties of commercial carbon nanofibers (CNFs) produced by chemical vapor deposition (CVD) depend on the various conditions used during their growth and post-growth synthesis, which also affect their derivate CNF-based textile fabrics. Here, the production and thermoelectric (TE) properties of cotton woven fabrics (CWFs) functionalized with aqueous inks made from different amounts of pyrolytically stripped (PS) Pyrograf((R)) III PR 25 PS XT CNFs via dipcoating method are presented. At 30 ffiC and depending on the CNF content used in the dispersions, the modified textiles show electrical conductivities ( sigma) varying between similar to 5 and 23 S m(-1) with a constant negative Seebeck coefficient (S) of 1.1 mu VK 1. Moreover, unlike the as-received CNFs, the functionalized textiles present an increase in their sigma from 30 ffi C to 100 degrees C (d sigma dT > 0), explained by the 3D variable range hopping (VRH) model as the charge carriers going beyond an aleatory network of potential wells by thermally activated hopping. However, as it happens with the CNFs, the dip-coated textiles show an increment in their S with temperature (dS/dT > 0) successfully fitted with the model proposed for some doped multiwall carbon nanotube (MWCNT) mats. All these results are presented with the aim of discerning the authentic function of this type of pyrolytically stripped Pyrograf((R)) III CNFs on the thermoelectric properties of their derived textiles.

Revista



Revista ISSN
Materials 1996-1944

Métricas Externas



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Disciplinas de Investigación



WOS
Materials Science, Multidisciplinary
Scopus
Materials Science (All)
Condensed Matter Physics
SciELO
Sin Disciplinas

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Publicaciones WoS (Ediciones: ISSHP, ISTP, AHCI, SSCI, SCI), Scopus, SciELO Chile.

Colaboración Institucional



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Autores - Afiliación



Ord. Autor Género Institución - País
1 Paleo, Antonio J. Hombre Univ Minho - Portugal
Universidade do Minho - Portugal
2 Krause, Beate Mujer Leibniz Inst Polymerforsch Dresden e V IPF - Alemania
Leibniz-Institut für Polymerforschung Dresden e.V. - Alemania
3 Cerqueira, Maria F. Mujer INL Int Iberian Nanotechnol Lab - Portugal
Univ Minho - Portugal
International Iberian Nanotechnology Laboratory - Portugal
Universidade do Minho - Portugal
4 Gonzalez-Dominguez, Jose M. Hombre Inst Carboquim ICB CSIC - España
CSIC - Instituto de Carboquimica (ICB) - España
5 MUNOZ-ORTIZ, ENRIQUE Hombre Pontificia Universidad Católica de Chile - Chile
6 Potschke, Petra Mujer Leibniz Inst Polymerforsch Dresden e V IPF - Alemania
Leibniz-Institut für Polymerforschung Dresden e.V. - Alemania
7 Rocha, Ana M. Mujer Univ Minho - Portugal
Universidade do Minho - Portugal

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Financiamiento



Fuente
Fundação para a Ciência e a Tecnologia
Fondo Nacional de Desarrollo Científico y Tecnológico
FONDECYT grant
FCT-Foundation for Science and Technology
European Cooperation in Science and Technology
European COST Action
Agencia Nacional de Investigación y Desarrollo
ANID PIA Anillo ACT
Short-Term Scientific Mission (STSM) at IPF (Dresden)

Muestra la fuente de financiamiento declarada en la publicación.

Agradecimientos



Agradecimiento
Antonio J. Paleo gratefully acknowledges support from the FCT-Foundation for Science and Technology by the "plurianual" 2020-2023 Project UIDB/00264/2020, and European COST Action EsSENce CA19118 for its support with the Short-Term Scientific Mission (STSM) at IPF (Dresden). E. Munoz acknowledges support from Fondecyt grant number 1230440 and from ANID PIA Anillo ACT/192023.
Antonio J. Paleo gratefully acknowledges support from the FCT-Foundation for Science and Technology by the “plurianual” 2020–2023 Project UIDB/00264/2020, and European COST Action EsSENce CA19118 for its support with the Short-Term Scientific Mission (STSM) at IPF (Dresden). E. Muñoz acknowledges support from Fondecyt grant number 1230440 and from ANID PIA Anillo ACT/192023.

Muestra la fuente de financiamiento declarada en la publicación.