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| Indexado |
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| DOI | 10.3390/MA16124335 | ||||
| Año | 2023 | ||||
| Tipo | artículo de investigación |
Citas Totales
Autores Afiliación Chile
Instituciones Chile
% Participación
Internacional
Autores
Afiliación Extranjera
Instituciones
Extranjeras
The transport properties of commercial carbon nanofibers (CNFs) produced by chemical vapor deposition (CVD) depend on the various conditions used during their growth and post-growth synthesis, which also affect their derivate CNF-based textile fabrics. Here, the production and thermoelectric (TE) properties of cotton woven fabrics (CWFs) functionalized with aqueous inks made from different amounts of pyrolytically stripped (PS) Pyrograf((R)) III PR 25 PS XT CNFs via dipcoating method are presented. At 30 ffiC and depending on the CNF content used in the dispersions, the modified textiles show electrical conductivities ( sigma) varying between similar to 5 and 23 S m(-1) with a constant negative Seebeck coefficient (S) of 1.1 mu VK 1. Moreover, unlike the as-received CNFs, the functionalized textiles present an increase in their sigma from 30 ffi C to 100 degrees C (d sigma dT > 0), explained by the 3D variable range hopping (VRH) model as the charge carriers going beyond an aleatory network of potential wells by thermally activated hopping. However, as it happens with the CNFs, the dip-coated textiles show an increment in their S with temperature (dS/dT > 0) successfully fitted with the model proposed for some doped multiwall carbon nanotube (MWCNT) mats. All these results are presented with the aim of discerning the authentic function of this type of pyrolytically stripped Pyrograf((R)) III CNFs on the thermoelectric properties of their derived textiles.
| Ord. | Autor | Género | Institución - País |
|---|---|---|---|
| 1 | Paleo, Antonio J. | Hombre |
Univ Minho - Portugal
Universidade do Minho - Portugal |
| 2 | Krause, Beate | Mujer |
Leibniz Inst Polymerforsch Dresden e V IPF - Alemania
Leibniz-Institut für Polymerforschung Dresden e.V. - Alemania |
| 3 | Cerqueira, Maria F. | Mujer |
INL Int Iberian Nanotechnol Lab - Portugal
Univ Minho - Portugal International Iberian Nanotechnology Laboratory - Portugal Universidade do Minho - Portugal |
| 4 | Gonzalez-Dominguez, Jose M. | Hombre |
Inst Carboquim ICB CSIC - España
CSIC - Instituto de Carboquimica (ICB) - España |
| 5 | MUNOZ-ORTIZ, ENRIQUE | Hombre |
Pontificia Universidad Católica de Chile - Chile
|
| 6 | Potschke, Petra | Mujer |
Leibniz Inst Polymerforsch Dresden e V IPF - Alemania
Leibniz-Institut für Polymerforschung Dresden e.V. - Alemania |
| 7 | Rocha, Ana M. | Mujer |
Univ Minho - Portugal
Universidade do Minho - Portugal |
| Fuente |
|---|
| Fundação para a Ciência e a Tecnologia |
| Fondo Nacional de Desarrollo Científico y Tecnológico |
| FONDECYT grant |
| FCT-Foundation for Science and Technology |
| European Cooperation in Science and Technology |
| European COST Action |
| Agencia Nacional de Investigación y Desarrollo |
| ANID PIA Anillo ACT |
| Short-Term Scientific Mission (STSM) at IPF (Dresden) |
| Agradecimiento |
|---|
| Antonio J. Paleo gratefully acknowledges support from the FCT-Foundation for Science and Technology by the "plurianual" 2020-2023 Project UIDB/00264/2020, and European COST Action EsSENce CA19118 for its support with the Short-Term Scientific Mission (STSM) at IPF (Dresden). E. Munoz acknowledges support from Fondecyt grant number 1230440 and from ANID PIA Anillo ACT/192023. |
| Antonio J. Paleo gratefully acknowledges support from the FCT-Foundation for Science and Technology by the “plurianual” 2020–2023 Project UIDB/00264/2020, and European COST Action EsSENce CA19118 for its support with the Short-Term Scientific Mission (STSM) at IPF (Dresden). E. Muñoz acknowledges support from Fondecyt grant number 1230440 and from ANID PIA Anillo ACT/192023. |