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| DOI | 10.1007/S10765-023-03211-4 | ||||
| Año | 2023 | ||||
| Tipo | artículo de investigación |
Citas Totales
Autores Afiliación Chile
Instituciones Chile
% Participación
Internacional
Autores
Afiliación Extranjera
Instituciones
Extranjeras
Experimental densities ? and sound speeds u at (293.15, 298.15, 303.15, 308.15, 313.15, and 318.15) K and refractive indices n(D) at 298.15 K are reported for the 1-propanol + cyclohexane, 1-propanol + cyclohexene, and 1-propanol + cyclohexanone binary mixtures covering the entire composition ranges and under atmospheric pressure. The excess molar volumes V-m(E), isentropic compressibility deviations ?K-S, and refractive index deviations ?n(D) were derived from the experimental data. Redlich-Kister polynomial was the mathematical model of choice to correlate the derived properties of the studied mixtures. In each case, the Redlich-Kister polynomial with an optimal number of parameters provided a statistically significant mathematical representation of the derived properties with standard deviations compared to the estimated expanded uncertainties of corresponding properties. Furthermore, the Perturbed Chain Statistical Associating Fluid Theory (PC-SAFT) was used to correctly model the density of pure fluids and mixtures, whereas the coupling of PC-SAFT with Schaaff's collision factor theory (SCFT) and Laplace mixing rules proved to be successful approaches for modeling the speed of sound and refractive index, respectively.
| Ord. | Autor | Género | Institución - País |
|---|---|---|---|
| 1 | HERNANDEZ-SEPULVEDA, ARIEL GONZALO | Hombre |
Universidad Católica de la Santísima Concepción - Chile
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| 2 | Zeqiraj, Arber Zymer | - |
Univ Isa Boletini Mitrovice - Kosovo
Universiteti “Isa Boletini” Mitrovicë - Kosovo |
| 3 | Aliaj, Fisnik Rrustem | - |
Univ Prishtines - Kosovo
Universiteti i Prishtines - Kosovo |