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Screen-printed nickel hydroxide electrodes: Semiconducting, electrocatalytic, and electrochromic properties
Indexado
WoS WOS:000897451500004
Scopus SCOPUS_ID:85143681689
DOI 10.1016/J.JELECHEM.2022.117052
Año 2023
Tipo artículo de investigación

Citas Totales

Autores Afiliación Chile

Instituciones Chile

% Participación
Internacional

Autores
Afiliación Extranjera

Instituciones
Extranjeras


Abstract



This work presents a methodology to develop functional metal-oxide based inks for screen-printing. Nickel hydroxide has been grown by co-precipitation on the surface of conducting microparticles using different par-ticle to nickel salt ratios. The resulting particles formed the basis of screen-printing inks, used to print elec-trodes and test structures. The work describes the characterization of the materials through the different stages of development using a range of techniques including SEM, TEM, electrochemical and spectroscopic techniques. The screen printed electrodes have demonstrated their ability to oxidise water at 0.7-0.8 V vs Ag, making them suitable for electrolyzers. Also, glucose can be directly oxidised at these electrodes below 0.6 V vs Ag, with a detection limit around 65 mu M, also pointing to enzyme-less biosensing applications. The electrodes also display electrochromism, with charge efficiencies in the range of 50 cm2 C-1. Last, the elec-trodes present an optical bandgap in the range 4.06-4.15 eV, determined by diffuse reflectance spectroscopy. The approach presented here is extensive to other metal oxides, which opens the range of possible screen -printed semiconductors and catalysts considerably.

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Disciplinas de Investigación



WOS
Chemistry, Analytical
Electrochemistry
Scopus
Electrochemistry
Chemical Engineering (All)
Analytical Chemistry
SciELO
Sin Disciplinas

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Publicaciones WoS (Ediciones: ISSHP, ISTP, AHCI, SSCI, SCI), Scopus, SciELO Chile.

Colaboración Institucional



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Autores - Afiliación



Ord. Autor Género Institución - País
1 Sanchez, Alaine - Univ Basque Country - España
Universidad del País Vasco - España
2 Esmail Shalan, Ahmed Hombre BCMaterials - España
BCMaterials - Basque Center for Materials, Applications and Nanostructures - España
2 Shalan, Ahmed Esmail Hombre BCMaterials - Basque Center for Materials, Applications and Nanostructures - España
BCMaterials - España
3 Rosales, M. - Universidad de Chile - Chile
Advanced Mining Technology Center - Chile
Centro Avanzado de Tecnologia para la Mineria - Chile
4 Ruiz de Larramendi, Idoia Mujer Univ Basque Country - España
Universidad del País Vasco - España
5 Javier del Campo, Francisco Hombre BCMaterials - España
Basque Fdn Sci - España
BCMaterials - Basque Center for Materials, Applications and Nanostructures - España
Ikerbasque, Basque Foundation for Science - España

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Financiamiento



Fuente
Spanish Ministry of Science and Innovation
European Regional Development Fund
Euskal Herriko Unibertsitatea
Ministerio de Ciencia e Innovación
European Social Fund
SGIker of UPV/EHU

Muestra la fuente de financiamiento declarada en la publicación.

Agradecimientos



Agradecimiento
Project number PID2020-113154RB-C22 from the Spanish Ministry of Science and Innovation is gratefully acknowledged. The authors are grateful for the technical and human support provided by SGIker of UPV/EHU and European funding (ERDF and ESF) . Jon Velasco's help during the revision of this manuscript is also gratefully acknowledged.
Project number PID2020-113154RB-C22 from the Spanish Ministry of Science and Innovation is gratefully acknowledged. The authors are grateful for the technical and human support provided by SGIker of UPV/EHU and European funding (ERDF and ESF). Jon Velasco's help during the revision of this manuscript is also gratefully acknowledged.

Muestra la fuente de financiamiento declarada en la publicación.