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| DOI | 10.1016/J.JELECHEM.2022.117052 | ||||
| Año | 2023 | ||||
| Tipo | artículo de investigación |
Citas Totales
Autores Afiliación Chile
Instituciones Chile
% Participación
Internacional
Autores
Afiliación Extranjera
Instituciones
Extranjeras
This work presents a methodology to develop functional metal-oxide based inks for screen-printing. Nickel hydroxide has been grown by co-precipitation on the surface of conducting microparticles using different par-ticle to nickel salt ratios. The resulting particles formed the basis of screen-printing inks, used to print elec-trodes and test structures. The work describes the characterization of the materials through the different stages of development using a range of techniques including SEM, TEM, electrochemical and spectroscopic techniques. The screen printed electrodes have demonstrated their ability to oxidise water at 0.7-0.8 V vs Ag, making them suitable for electrolyzers. Also, glucose can be directly oxidised at these electrodes below 0.6 V vs Ag, with a detection limit around 65 mu M, also pointing to enzyme-less biosensing applications. The electrodes also display electrochromism, with charge efficiencies in the range of 50 cm2 C-1. Last, the elec-trodes present an optical bandgap in the range 4.06-4.15 eV, determined by diffuse reflectance spectroscopy. The approach presented here is extensive to other metal oxides, which opens the range of possible screen -printed semiconductors and catalysts considerably.
| Ord. | Autor | Género | Institución - País |
|---|---|---|---|
| 1 | Sanchez, Alaine | - |
Univ Basque Country - España
Universidad del País Vasco - España |
| 2 | Esmail Shalan, Ahmed | Hombre |
BCMaterials - España
BCMaterials - Basque Center for Materials, Applications and Nanostructures - España |
| 2 | Shalan, Ahmed Esmail | Hombre |
BCMaterials - Basque Center for Materials, Applications and Nanostructures - España
BCMaterials - España |
| 3 | Rosales, M. | - |
Universidad de Chile - Chile
Advanced Mining Technology Center - Chile Centro Avanzado de Tecnologia para la Mineria - Chile |
| 4 | Ruiz de Larramendi, Idoia | Mujer |
Univ Basque Country - España
Universidad del País Vasco - España |
| 5 | Javier del Campo, Francisco | Hombre |
BCMaterials - España
Basque Fdn Sci - España BCMaterials - Basque Center for Materials, Applications and Nanostructures - España Ikerbasque, Basque Foundation for Science - España |
| Fuente |
|---|
| Spanish Ministry of Science and Innovation |
| European Regional Development Fund |
| Euskal Herriko Unibertsitatea |
| Ministerio de Ciencia e Innovación |
| European Social Fund |
| SGIker of UPV/EHU |
| Agradecimiento |
|---|
| Project number PID2020-113154RB-C22 from the Spanish Ministry of Science and Innovation is gratefully acknowledged. The authors are grateful for the technical and human support provided by SGIker of UPV/EHU and European funding (ERDF and ESF) . Jon Velasco's help during the revision of this manuscript is also gratefully acknowledged. |
| Project number PID2020-113154RB-C22 from the Spanish Ministry of Science and Innovation is gratefully acknowledged. The authors are grateful for the technical and human support provided by SGIker of UPV/EHU and European funding (ERDF and ESF). Jon Velasco's help during the revision of this manuscript is also gratefully acknowledged. |