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| DOI | 10.1016/J.MATERRESBULL.2023.112221 | ||||
| Año | 2023 | ||||
| Tipo | artículo de investigación |
Citas Totales
Autores Afiliación Chile
Instituciones Chile
% Participación
Internacional
Autores
Afiliación Extranjera
Instituciones
Extranjeras
The mixed ionic and electronic conductor oxide with formula Sr2-xLaxSnO4 (S2LS) within x ≤ 0.10 were synthesized via the conventional ceramic route and investigated. The structural analysis revealed the formation of single-phase materials with a tetragonal crystal structure. The presence of Sn in the form of Sn4+/Sn2+ ions and oxygen vacancies in the synthesized samples were investigated by X-ray photoelectron spectroscopy. The alternating current (AC) conductivity and modulus spectra of S2LS systems were obtained as functions of frequency and temperature and further scaled. The AC conductivity data were analyzed using Jonscher's power law (JPL) fitting to determine the hopping frequencies, DC conductivities, and power exponents. The obtained activation energy value suggests the dependence of conductivity primarily on the mobility of charge carriers. The conductivity spectra were analyzed using various formalisms, viz., Ghosh scaling and Rolling scaling, to understand the conduction mechanism. The scaling behaviors of AC conductivity and modulus spectra reflect the temperature-independent conduction mechanism of the system.
| Ord. | Autor | Género | Institución - País |
|---|---|---|---|
| 1 | Kumar, Upendra | - |
Indian Institute of Information Technology, Allahabad - India
IIIT Allahabad - India |
| 2 | Jatiya, Manisha | Mujer |
Indian Institute of Information Technology, Allahabad - India
IIIT Allahabad - India |
| 3 | FLORES-GARCIA, MARCOS ALEXIS | Hombre |
Universidad de Chile - Chile
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| Fuente |
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| Science and Engineering Research Board (SERB) |
| Science and Engineering Research Board |
| CIF-IIT-BHU |
| Agradecimiento |
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| The author is thankful to Dr. (Mrs.) Shail Upadhyay for providing a research facility to synthesize and characterize the system. The author also acknowledged the CIF-IIT-BHU for providing SEM characterization. The authors, Mr. Upendra Kumar and Ms. Manisha Jatiya, acknowledge the Science and Engineering Research Board (SERB) for the research grant (File No.: SERB/EEQ/2021/000132). |
| The author is thankful to Dr. (Mrs.) Shail Upadhyay for providing a research facility to synthesize and characterize the system. The author also acknowledged the CIF-IIT-BHU for providing SEM characterization. The authors, Mr. Upendra Kumar and Ms. Manisha Jatiya, acknowledge the Science and Engineering Research Board (SERB) for the research grant (File No.: SERB/EEQ/2021/000132). |
| The author is thankful to Dr. (Mrs.) Shail Upadhyay for providing a research facility to synthesize and characterize the system. The author also acknowledged the CIF-IIT-BHU for providing SEM characterization. The authors, Mr. Upendra Kumar and Ms. Manisha Jatiya, acknowledge the Science and Engineering Research Board (SERB) for the research grant (File No.: SERB/EEQ/2021/000132) . |