Electrically conductive polymeric materials are increasing rapidly due to their potential applications in electrical and electronics areas. Recently, environmental and ecosystem sustainable developments have demanded the use of electrically conducting biodegradable polymeric systems. In this context, the advancement in electrically conducting systems such as cyclopolymerized 1,6-heptadienes and their derivatives is described. Further, the report suggests the 1,6-heptadienes can be realized as biodegradable 1,6-heptadienes using various synthetic methods. In addition, the necessity for electrically conducting biodegradable and biocompatible polymeric systems, and their applications is highlighted. Furthermore, this chapter expounds on biodegradable polymeric systems with extensive functionalities facilitated for eco-friendly and sustainable development. © 2022 Copyright