The trend to reduce CO2 emissions in cooling processes has made it possible to increase the alternatives for integrating solar energy with thermal equipment whose viability depends on its adaptation to polygeneration schemes. Despite the enormous potential offered by the industry for cooling and heating processes, solar cooling technologies (SCT) have been explored in a limited way in the industrial sector. This work discusses the potential applications of industrial SCTs and classifies hybrid polygeneration schemes based on supplying cold, heat, electricity, and desalination of water; summarizes the leading SCTs, and details the main indicators of polygeneration configurations in terms of reductions on primary energy consumption and payback times. To achieve an energy transition in refrigeration processes, the scenarios with the most significant potential are: the food manufacturing industry (water immersion and crystallization processes), the beverage industry (fermentation and storage processes), and the mining industry (underground air conditioning).