We introduce a novel procedure for studying the Hamiltonian formalism of new general relativity (NGR) based on the mathematical properties encoded in the constitutive tensor defined by the premetric approach. We derive the canonical momenta conjugate to the tetrad field and study the eigenvalues of the Hessian tensor, which is mapped to a Hessian matrix with the help of indexation formulas. The properties of the Hessian matrix heavily rely on the possible values of the free coefficients ci,i = 1, 2, 3 appearing in the NGR Lagrangian. We find four null eigenvalues associated with trivial primary constraints in the temporal part of the momenta. The remaining eigenvalues are grouped in four sets, which have multiplicity 3, 1, 5 and 3, and can be set to zero depending on different choices of the coefficients ci. There are nine possible different cases when one, two, or three sets of eigenvalues are imposed to vanish simultaneously. All cases lead to a different number of primary constraints, which are consistent with previous work on the Hamiltonian analysis of NGR by Blixt et al. (2018).