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| DOI | 10.1016/J.FLUID.2020.112864 | ||||
| Año | 2021 | ||||
| Tipo | artículo de investigación |
Citas Totales
Autores Afiliación Chile
Instituciones Chile
% Participación
Internacional
Autores
Afiliación Extranjera
Instituciones
Extranjeras
The modeling of the density, viscosity and electrical conductivity of aqueous solutions saturated with boric acid, in the presence of sodium sulfate or lithium sulfate, are presented. The salt concentrations range studied were from (0 to 3.3242) mol kg(-1) for sodium sulfate and from (0 to 2.9336) mol kg(-1) for lithium sulfate at temperatures from (293.15 to 313.15) K and at 1 atm pressure. A model for the density was derived using the Pitzer model. The Eyring's absolute rate theory and the Pitzer model were combined to represent the viscosity. The Casteel-Amis equation was modified to describe the electrical conductivity with temperature and boric acid effects where necessary. The results showed that the models successfully represented the properties studied and are robust for estimation purposes within and beyond the experimental range studied. Also, it was found that short range interactions of boric acid, sulfate, sodium and lithium ions with water molecules are relevant to determine the volumetric and transport properties of these solutions and that the electrical conductivity is determined by charged species (Na+, SO42- NaSO4-, HSO4- and Li+, SO42-, LiSO4-) and the solution viscosity; that is mainly influenced by these salts concentrations, boric acid solubility behavior with these salts and temperature. This is valuable information to improve the processes of boric acid production. (C) 2020 Elsevier B.V. All rights reserved.
| Ord. | Autor | Género | Institución - País |
|---|---|---|---|
| 1 | ALAVIA-MEDINA, WILSON | Hombre |
Universidad Tecnológica Metropolitana - Chile
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| 2 | LOVERA-COPA, JORGE ALFREDO | Hombre |
Univ Tecn Oruro - Bolivia
Universidad Técnica de Oruro - Bolivia |
| 3 | GRABER-SEGUEL, TEOFILO ARNOLDO | Hombre |
Universidad de Antofagasta - Chile
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| 4 | Azua, Daniela | Mujer |
Universidad de Santiago de Chile - Chile
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| 5 | Soto, Ismael | Hombre |
Universidad de Santiago de Chile - Chile
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| Fuente |
|---|
| Fondo Nacional de Desarrollo Científico y Tecnológico |
| Comisión Nacional de Investigación Científica y Tecnológica |
| Universidad de Antofagasta |
| CICITEM |
| CICITEM Project |
| ANID |
| Agencia de Innovación y Desarrollo de Andalucía |
| (Agencia Nacional de Investigacion y Desarrollo, ANID, Chile) through the FONDECYT Project |
| Project Bridge Universidad de Antofagasta |
| Agradecimiento |
|---|
| The authors are grateful for the funding provided by CONICYT (current Agencia Nacional de Investigacion y Desarrollo, ANID, Chile) through the FONDECYT Project No.1120192, CICITEM Project R04I1001 and Project Bridge Universidad de Antofagasta. |
| The authors are grateful for the funding provided by CONICYT (current Agencia Nacional de Investigación y Desarrollo, ANID, Chile) through the FONDECYT Project No.1120192, CICITEM Project R04I1001 and Project Bridge Universidad de Antofagasta. |