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| DOI | 10.1002/CELC.202000782 | ||||
| Año | 2020 | ||||
| Tipo | artículo de investigación |
Citas Totales
Autores Afiliación Chile
Instituciones Chile
% Participación
Internacional
Autores
Afiliación Extranjera
Instituciones
Extranjeras
In this work we report a simple and cost-effective CsPbBr3-based solar cell without ordinary selective contacts. To do so we follow an electrochemical approach consisting of three successive steps: (1) electrodeposition of PbO(2)directly on top of FTO substrates, (2) heterogeneous phase reaction with gaseous HBr and (3) spin-coating of methanolic CsBr solutions followed by annealing. This method is more adequate for large-scale environmentally friendly production as it reduces chemical waste, particularly toxic lead. The resulting films were structurally and optically characterized showing good coverage of the FTO substrates, absence of defects such as pinholes and orthorhombic structure. Photovoltaic and impedance characterization was carried out by pressing a carbon coated metal spring onto the CsPbBr(3)film until obtaining maximized open-circuit potential (V-oc) and short-circuit photocurrent density (j(sc)) under simulated sunlight. The stabilized current at fixed voltage (SCFV) technique gave a maximum PCE value of 2.70 % close to devices with similar configuration. Impedance measurements demonstrated analogous behavior to that of state-of-art CsPbBr(3)based solar cells, comprising a recombination arc at mid-high frequencies, geometrical capacitance and ideality factors closed to 2, typical of SRH recombination in the perovskite bulk.
| Ord. | Autor | Género | Institución - País |
|---|---|---|---|
| 1 | RAMIREZ-RUIZ, DANIEL LUIS | Hombre |
Universidad de Valparaíso - Chile
|
| 2 | RIVEROS-PATRONI, GONZALO ANTONIO | Hombre |
Universidad de Valparaíso - Chile
|
| 3 | Díaz, Patricia | Mujer |
Universidad de Valparaíso - Chile
|
| 4 | Verdugo, Javier | Hombre |
Universidad de Valparaíso - Chile
|
| 5 | Nunez, Gerard | Hombre |
Universidad de Valparaíso - Chile
|
| 6 | Lizama, Susy | Mujer |
Universidad de Valparaíso - Chile
|
| 7 | Lazo, Pamela | Mujer |
Universidad de Valparaíso - Chile
|
| 8 | Dalchiele, E. A. | Hombre |
UNIV REPUBLICA - Uruguay
Universidad La República - Uruguay Universidad de la República - Uruguay |
| 9 | Gau, Daniel L. | Hombre |
UNIV REPUBLICA - Uruguay
Universidad La República - Uruguay Universidad de la República - Uruguay |
| 10 | Marotti, Ricardo E. | Hombre |
UNIV REPUBLICA - Uruguay
Universidad La República - Uruguay Universidad de la República - Uruguay |
| 11 | Anta, Juan | Hombre |
Univ Pablo Olavide - España
Universidad Pablo de Olavide - España Universidad Pablo de Olavide, de Sevilla - España |
| 12 | Contreras-Bernal, Lidia | Mujer |
Univ Pablo Olavide - España
Universidad Pablo de Olavide - España Universidad Pablo de Olavide, de Sevilla - España |
| 13 | Riquelme, Antonio | Hombre |
Univ Pablo Olavide - España
Universidad Pablo de Olavide - España Universidad Pablo de Olavide, de Sevilla - España |
| 14 | Idigoras, Jesus | Hombre |
Univ Pablo Olavide - España
Universidad Pablo de Olavide - España Universidad Pablo de Olavide, de Sevilla - España |
| Fuente |
|---|
| Comisión Nacional de Investigación Científica y Tecnológica |
| Universidad de Valparaíso |
| Santander Universidades |
| Ministry of Education of Spain |
| Universidad de Valpara?so |
| FONDECYT/ANID |
| Comisión Nacional de Investigación Científica y Tecnológica |
| Agradecimiento |
|---|
| To FONDECYT/ANID project number 1200974. J.A.A. and D.R. also acknowledge to MEC80180057 project (CONICYT), to Santander Universidades project and to Division Academica from Universidad de Valparaiso. The authors especially thanks to B. Cadiz and M. Verdugo for optical imaging of the electric contact area in samples. L. Hernandez and M. Kulbak are also acknowledged for non-aqueous electrochemistry facilities and fruitful discussions in experiments design respectively. A.R. thanks Ministry of Education of Spain for an FPU grant. |
| To FONDECYT/ANID project number 1200974. J.A.A. and D.R. also acknowledge to MEC80180057 project (CONICYT), to Santander Universidades project and to División Académica from Universidad de Valparaíso. The authors especially thanks to B. Cádiz and M. Verdugo for optical imaging of the electric contact area in samples. L. Hernández and M. Kulbak are also acknowledged for non-aqueous electrochemistry facilities and fruitful discussions in experiments design respectively. A.R. thanks Ministry of Education of Spain for an FPU grant. |