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| DOI | 10.1088/2515-7639/AB0A3E | ||||
| Año | 2019 | ||||
| Tipo | artículo de investigación |
Citas Totales
Autores Afiliación Chile
Instituciones Chile
% Participación
Internacional
Autores
Afiliación Extranjera
Instituciones
Extranjeras
Shift current-a photocurrent induced by light irradiating noncentrosymmetric materials in the absence of any bias voltage or built-in electric field-is one of the mechanisms of the so-called bulk photovoltaic effect. It has been traditionally described as a nonlinear optical response of a periodic solid to continuous wave light using a perturbative formula, which is linear in the intensity of light and which involves Berry connection describing the shift in the center of mass position of the Wannier wave function associated with the transition between the valence and conduction bands of the solid. Since shift current is solely due to off-diagonal elements of the nonequilibrium density matrix that encode quantum correlations, its peculiar space-time dynamics in response to femtosecond light pulse employed locally can be expected. To study such response requires to analyze realistic two-terminal devices, instead of traditional periodic solids, for which we choose paradigmatic Rice-Mele model sandwiched between two metallic electrodes and apply to it time-dependent nonequilibrium Green function algorithms scaling linearly in the number of time steps and capable of treating nonperturbative effects in the amplitude of external time-dependent fields. This reveals novel features:superballistictransport, signified by time dependence of the displacement, similar to t(nu)with nu > 1, of the photoexcited charge carriers from the spot where the femtosecond light pulse is applied toward the electrodes; and photocurrent quadratic in light intensity at subgap frequencies of light due totwo-photon absorptionprocesses that were missed in previous perturbative analyses. Furthermore, frequency dependence of the DC component of the photocurrent reveals shift current as a realization of nonadiabatic quantum charge pumping enabled bybreaking of left-right symmetryof the device structure. This demonstrates that a much wider class of systems, than the usually considered polar noncentrosymmetric bulk materials, can be exploited to generate nonzero DC component of photocurrent in response to unpolarized light and optimize shift-current-based solar cells and optoelectronic devices.
| Ord. | Autor | Género | Institución - País |
|---|---|---|---|
| 1 | Bajpai, U. | - |
Univ Delaware - Estados Unidos
University of Delaware - Estados Unidos |
| 2 | Popescu, B. S. | - |
Univ Delaware - Estados Unidos
University of Delaware - Estados Unidos |
| 3 | Plechac, P. | - |
Univ Delaware - Estados Unidos
University of Delaware - Estados Unidos |
| 4 | Nikolic, B. K. | - |
Univ Delaware - Estados Unidos
RIKEN Ctr Emergent Matter Sci CEMS - Japón University of Delaware - Estados Unidos RIKEN - Japón |
| 5 | FOA-TORRES, LUIS EDUARDO FRANCISCO | Hombre |
Universidad de Chile - Chile
|
| 6 | Ishizuka, H. | - |
Univ Tokyo - Japón
The University of Tokyo - Japón |
| 7 | Nagaosa, N. | - |
RIKEN Ctr Emergent Matter Sci CEMS - Japón
Univ Tokyo - Japón RIKEN - Japón The University of Tokyo - Japón |
| Fuente |
|---|
| National Science Foundation |
| Fondo Nacional de Desarrollo Científico y Tecnológico |
| FONDECYT (Chile) |
| NSF |
| Core Research for Evolutional Science and Technology |
| Japan Science and Technology Agency |
| Japan Society for the Promotion of Science |
| Council for Science, Technology and Innovation |
| Army Research Office |
| Japan Society for the Promotion of Science KAKENHI |
| ImPACT Program of Council for Science, Technology and Innovation (Cabinet office, Government of Japan) |
| CREST, Japan Science and Technology |
| ARO MURI Award |
| Agradecimiento |
|---|
| UB, BSP and BKN were supported by NSF grant No. CHE 1566074. PP was supported by ARO MURI Award No. W911NF-14-0247. LEFFT was supported by FondeCyT grant No. 1170917 (Chile). HI and NN were supported by Japan Society for the Promotion of Science KAKENHI (grants No. JP16H06717 and JP26103006); ImPACT Program of Council for Science, Technology and Innovation (Cabinet office, Government of Japan, 888176); and CREST, Japan Science and Technology (grant no. JPMJCR16F1). This work used the Extreme Science and Engineering Discovery Environment (XSEDE), which is supported by NSF grant No. ACI-1548562. |
| UB, BSP and BKN were supported by NSF grant No. CHE 1566074. PP was supported by ARO MURI Award No. W911NF-14-0247. LEFFT was supported by FondeCyT grant No. 1170917 (Chile). HI and NN were supported by Japan Society for the Promotion of Science KAKENHI (grants No. JP16H06717 and JP26103006); ImPACT Program of Council for Science, Technology and Innovation (Cabinet office, Government of Japan, 888176); and CREST, Japan Science and Technology (grant no. JPMJCR16F1). This work used the Extreme Science and Engineering Discovery Environment (XSEDE), which is supported by NSF grant No. ACI-1548562. |