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| DOI | 10.1016/J.ENMM.2015.11.001 | ||
| Año | 2016 | ||
| Tipo |
Citas Totales
Autores Afiliación Chile
Instituciones Chile
% Participación
Internacional
Autores
Afiliación Extranjera
Instituciones
Extranjeras
In this study, degradation of an industrial textile dye by electrochemical oxidation (EO) approach has been performed in an aqueous medium. The galvanostatic electrolysis, through the use of the platinum supported on Ti (Ti/Pt), lead dioxide (Pb/PbO2) and TiO2-nanotubes decorated with PbO2 supported on Ti (Ti/TiO2-nanotubes/PbO2) anodes, were conducted in an electrochemical flow cell with 1.0 L of solution containing 250 mg dm-3 of the textile dye Acid Blue 113 (AB113) using Na2SO4 as supporting electrolyte, applying 20, 40 and 60 mA cm-2. Large disk electrodes of Ti/TiO2-Nanotubes/PbO2 (65 cm2 of geometrical area) were successfully synthesized by anodization and electrodeposition procedures. The electrolytic process was monitored by the UV-visible spectrometry and the chemical oxygen demand (COD). The results showed that the AB113 was successfully degraded by hydroxyl radicals electrogenerated from water discharge on the Ti/TiO2-Nanotubes/PbO2 electrode surface. Compared with Ti/Pt and Pb/PbO2, the Ti/TiO2-Nanotubes/PbO2 anode showed a better performance to remove the AB113. It provided a higher oxidation rate, higher current efficiency and consumed less energy than the galvanostatic electrolysis using the other electrodes.
| Ord. | Autor | Género | Institución - País |
|---|---|---|---|
| 1 | Moura, Dayanne Chianca De | - |
Universidade Federal do Rio Grande do Norte - Brasil
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| 2 | Quiroz, Marco Antonio | Hombre |
Universidad de Las Américas, México - México
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| 3 | Silva, Djalma Ribeiro Da | - |
Universidade Federal do Rio Grande do Norte - Brasil
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| 4 | Salazar, Ricardo | Hombre |
Universidad de Santiago de Chile - Chile
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| 5 | Martínez-Huitle, Carlos Alberto | Hombre |
Universidade Federal do Rio Grande do Norte - Brasil
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| Fuente |
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| Conselho Nacional de Desenvolvimento Científico e Tecnológico |
| Coordenação de Aperfeiçoamento de Pessoal de Nível Superior |
| Coordenação de Aperfeiçoamento de Pessoal de NÃvel Superior |
| Conselho Nacional de Desenvolvimento CientÃfico e Tecnológico |
| Industrie De Nora S.p.A. |
| Agradecimiento |
|---|
| The authors thank the financial support provided by CAPES and they also thank Industrie De Nora S.p.A. (Milan, Italy) for providing the Ti/Pt electrode. C.A. Martínez-Huitle thanks funding from the National Council for Scientific and Technological Development ( CNPq-446846/2014-7 and CNPq-401519/2014-7 , Brazil). |