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| DOI | 10.1063/1.5136320 | ||||
| Año | 2020 | ||||
| Tipo | artículo de investigación |
Citas Totales
Autores Afiliación Chile
Instituciones Chile
% Participación
Internacional
Autores
Afiliación Extranjera
Instituciones
Extranjeras
This is a tutorial-style introduction to the field of molecular polaritons. We describe the basic physical principles and consequences of strong light-matter coupling common to molecular ensembles embedded in UV-visible or infrared cavities. Using a microscopic quantum electrodynamics formulation, we discuss the competition between the collective cooperative dipolar response of a molecular ensemble and local dynamical processes that molecules typically undergo, including chemical reactions. We highlight some of the observable consequences of this competition between local and collective effects in linear transmission spectroscopy, including the formal equivalence between quantum mechanical theory and the classical transfer matrix method, under specific conditions of molecular density and indistinguishability. We also overview recent experimental and theoretical developments on strong and ultrastrong coupling with electronic and vibrational transitions, with a special focus on cavity-modified chemistry and infrared spectroscopy under vibrational strong coupling. We finally suggest several opportunities for further studies that may lead to novel applications in chemical and electromagnetic sensing, energy conversion, optoelectronics, quantum control, and quantum technology. Published under license by AIP Publishing.
| Ord. | Autor | Género | Institución - País |
|---|---|---|---|
| 1 | HERRERA-DIAZ, FRANCISCO | Hombre |
Universidad de Santiago de Chile - Chile
Millennium Inst Res Opt MIRO - Chile Instituto Milenio de Investigación en Óptica - Chile |
| 2 | Owrutsky, Jeffrey | Hombre |
US Naval Res Lab - Estados Unidos
Naval Research Laboratory - Estados Unidos U.S. Naval Research Laboratory - Estados Unidos |
| Fuente |
|---|
| Fondo Nacional de Desarrollo Científico y Tecnológico |
| Comisión Nacional de Investigación Científica y Tecnológica |
| Iniciativa Científica Milenio |
| Fondecyt Regular |
| Comisión Nacional de Investigación CientÃfica y Tecnológica |
| Iniciativa Cientifica Milenio (ICM) through the Millennium Institute for Research in Optics (MIRO) |
| Office of Naval Research |
| CONICYT through the Proyecto REDES ETAPA INICIAL |
| U.S. Naval Research Laboratory |
| Office of Naval Research through internal funding at the U.S. Naval Research Laboratory |
| Agradecimiento |
|---|
| We are thankful to Blake Simpkins, Adam Dunkelberger, Andrea Grafton, Ivan Jara, Federico Hernandez, and Johan Triana for valuable discussions. F.H. was supported by CONICYT through the Proyecto REDES ETAPA INICIAL, Convocatoria 2017 No. REDI 170423, FONDECYT Regular No. 1181743, and Iniciativa Cientifica Milenio (ICM) through the Millennium Institute for Research in Optics (MIRO). J.O. was supported by the Office of Naval Research through internal funding at the U.S. Naval Research Laboratory. |
| We are thankful to Blake Simpkins, Adam Dunkelberger, Andrea Grafton, Iván Jara, Federico Hernández, and Johan Triana for valuable discussions. F.H. was supported by CONICYT through the Proyecto REDES ETAPA INICIAL, Convocatoria 2017 No. REDI 170423, FONDECYT Regular No. 1181743, and Iniciativa Científica Milenio (ICM) through the Millennium Institute for Research in Optics (MIRO). J.O. was supported by the Office of Naval Research through internal funding at the U.S. Naval Research Laboratory. |