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Catalytic performance of 2D-Mxene nano-sheets for the hydrodeoxygenation (HDO) of lignin-derived model compounds
| Indexado |
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| DOI | 10.1016/J.CATCOM.2019.105833 | ||||
| Año | 2020 | ||||
| Tipo | artículo de investigación |
Citas Totales
Autores Afiliación Chile
Instituciones Chile
% Participación
Internacional
Autores
Afiliación Extranjera
Instituciones
Extranjeras
Abstract
2D Mxene nano-sheets (Ti3C2Tx) were investigated for the hydrodeoxygenation of guaiacol as a lignin-derived model compound. The catalyst was characterized by TEM, XPS, Raman spectroscopy and TPR. The acid-base properties were measured by TPD-NH3 and TPRe-MeOH. Phenol was the main product obtained, and methylanisole was observed as the second main product. The study of Anisole conversion shows that methylanisole was likely obtained by a bimolecular transalkylation. Such formation, which has only been reported over acid catalysts, was associated to the combined action of acid-base pairs identified.
| Ord. | Autor | Género | Institución - País |
|---|---|---|---|
| 1 | BLANCO-LORENZO, ELISA MACARENA | Mujer |
Pontificia Universidad Católica de Chile - Chile
Núcleo Milenio en procesos Catalíticos hacia la química Sustentable - Chile |
| 2 | Rosenkranz, Andreas | Hombre |
Universidad de Chile - Chile
|
| 3 | GONZALEZ-ARANDA, RODRIGO ANDRES | Hombre |
Universidad de Chile - Chile
|
| 4 | FUENZALIDA-ESCOBAR, VICTOR MANUEL | Hombre |
Universidad de Chile - Chile
|
| 5 | Zhang, Zhenyu | - |
Dalian Univ Technol - China
Dalian University of Technology - China |
| 6 | Suarez, Sebastian | Hombre |
Saarland Univ - Alemania
Universität des Saarlandes - Alemania |
| 7 | ESCALONA-BURGOS, NESTOR GUILLERMO | Hombre |
Pontificia Universidad Católica de Chile - Chile
Núcleo Milenio en procesos Catalíticos hacia la química Sustentable - Chile Universidad de Concepción - Chile Unidad de Desarollo Tecnhológico - Chile |
| Fuente |
|---|
| Universidad de Chile |
| China Scholarship Council |
| Ministerio de Economía, Fomento y Turismo |
| Fondo Nacional de Desarrollo Científico y Tecnológico |
| Comisión Nacional de Investigación Científica y Tecnológica |
| Universidad Austral de Chile |
| Conicyt Chile |
| African Mathematics Millennium Science Initiative |
| VID of Universidad de Chile |
| Millennium Science Initiative of the Chilean Ministry of Economy, Development, and Tourism |
| Chilean Ministry of Economy, Development |
| Nuclei on Catalytic Processes towards Sustainable Chemistry |
| Ministry of Economy, Development, and Tourism |
| Agradecimiento |
|---|
| The authors gratefully acknowledge funding from CONICYT Chile for the following projects: Fondecyt No 3170072, no 1180982, no 11180121, PIA CCTE AFB170007 and Fondequip N EQM160070. A. Rosenkranz greatly acknowledge the financial support given by the VID of Universidad de Chile in the framework of "U-Inicia UI013/2018." Additional funding was provided under the Millennium Science Initiative of the Chilean Ministry of Economy, Development, and Tourism, for the grant "Nuclei on Catalytic Processes towards Sustainable Chemistry (CSC)." |
| The authors gratefully acknowledge funding from CONICYT Chile for the following projects: Fondecyt N? 3170072, n?1180982, n?11180121, PIA CCTE AFB170007 and Fondequip N? EQM160070. A. Rosenkranz greatly acknowledge the financial support given by the VID of Universidad de Chile in the framework of ?U-Inicia UI013/2018.? Additional funding was provided under the Millennium Science Initiative of the Chilean Ministry of Economy, Development, and Tourism, for the grant ?Nuclei on Catalytic Processes towards Sustainable Chemistry (CSC).? |
