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| DOI | 10.1179/1743278211Y.0000000009 | ||||
| Año | 2011 | ||||
| Tipo | artículo de investigación |
Citas Totales
Autores Afiliación Chile
Instituciones Chile
% Participación
Internacional
Autores
Afiliación Extranjera
Instituciones
Extranjeras
The dependence of the corrosion rate on cell current density (CD) for three anode materials (Pb-Ca-Sn, RuO2-IrO2/Ti and IrO2-Ta2O5/Ti) in a laboratory scale copper electrowinning cell has been studied by means of short term weight loss tests, scanning electron microscopy observations and energy dispersive spectroscopy analysis. The lead anodes (Pb-Ca-Sn) corroded at all the studied cell CDs, and their corrosion rate increased with increasing cell CD. The precious metal oxide anodes (RuO2-IrO2 and IrO2-Ta2O5) only exhibited corrosion at the highest tested cell CD (1000 A m(-2)), and their corrosion rates were about a quarter of the lead corrosion rate at the same cell CD. The electrocatalytic properties of the three anode materials were characterised by means of potentiodynamic experiments. The overall results pointed to IrO2-Ta2O5/Ti as the best anode material of choice, although plant tests would be required before deciding on any specific commercial use.
| Ord. | Autor | Género | Institución - País |
|---|---|---|---|
| 1 | CIFUENTES-SEVES, LUIS | Hombre |
Universidad de Chile - Chile
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| 2 | Montes, A. | - |
Universidad de Chile - Chile
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| 3 | CRISOSTOMO, GLORIA | Mujer |
Universidad de Chile - Chile
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| Agradecimiento |
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| This work was funded by the CONICYT Chilean government agency via FONDECYT project nos. 108 5175 and 106 1160. Thanks are due to A. Parra, M. Farias and M. Ortega for their contribution to the authors' work on Cu electrowinning anodes. Continuous support by the Mining Engineering Department, Universidad de Chile, is gratefully acknowledged. |